Page 96 - Basic Gas Chromatography
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Inlets   83  Columns  Special      the   of  majority   the  samples,  most   For   dual  constants.  distribution  relative   their   Chapter   in  calculations   the   (see   phase  stationary   the   into   go   will  sample   helium   for  column  commercial   a  purchasing  When  column.   on  name   the  hence   3);   that  column   of  length   the  specify   to  necessary   is   it  injection,  on-column   just  requirements  geometric

   and   including   and   conductivity   irregular—usually   [5].   is   to   inadequate   other   ionization   accomplished   shown   the   on-column   in   by   port,   packing—ideally   depending
   Columns    TCD   a   thermal   possible   hydrogen   solutions   is   this   In   the   of   available   often   as  septum   with   modes:   shown   as   just  reached   the   into   column.   the   Gas   injection.



   Packed   arrangements   with   Hydrogen’s   are   often   not   are   and  helium   possible  some   [6].   TCD   the   universal.   one   commercially   SOLUTIONS   columns   is   silicone   colinearly   injection   positioned   position   go   will   it   column   the   packing   in   evaporated   Carrier   Glass   Wool   on-column



         column   analyzed   be   shapes   results   of   and   monograph   needed,   not   is   it   analysis,   gas   are   AND   packed   self-sealing   lined   is   up   possible   is   at   a   as   as   far   of   part   the   hold   column   or           |   for   port


         specialized   cannot   gas  mixture.   the   peak   quantitative   mixtures   discussion   Thompson’s   is  detector   because   environmental   There   [7].  need   SAMPLES   on   a   column   two   of   the  column   beginning   pushed   first   the   used   to   the   onto   Heated   injection




         for   that   a   in   that   thus   binary   of   More   in   satisfactory   preferable.   this   liquids   for   through   the   either   operation,   packing   syringe   is   into   plug   sorbed   Simplified
         used   sample   hydrogen   helium’s   function.   found   sensitive   not   in   met   LIQUID   figure,   for   delivered   wool   be
         be   operation.   of   W-shape—and   conductivity   be   more   occur   is   have   introduction   microsyringe   this   column   the   be   will   Syringe   5.8.
         can   type   is   gas   to   linear   can   a   often   is   might   detectors   that   FOR   5.8.   In   providing   vaporization.   on-column   the   When   will   glass   Fig.
         elements   column   One   carrier   close   so   a   thermal   problem   When   FID   as   detectors   INLETS   Sample   a   For   with   contents   small   analytes

  82              is   with   simple   the   such   tion   with   Figure   needle   flash   5.8   needle.   a   on   the
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