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72   Chapter Three


           3.3  Overall Process of Bioethanol
           Production
           The process of ethanol production depends on the raw materials used.
           Ageneral simplified representation of these processes is shown in Fig. 3.3,
           and a brief description of different units of the process is presented in
           the rest of this chapter. It should be noted that if sugar substances,
           such as molasses and sugarcane juice, are used as raw materials, then
           milling, pretreatment, hydrolysis, and detoxification are not necessary.
             Milling, liquefaction, and saccharification processes are usually nec-
           essary for production of fermentable sugar from starchy materials, while
           milling, pretreatment, and hydrolysis are typically used for ethanol pro-
           duction from lignocellulosic materials. Furthermore, a detoxification
           unit is not always considered, unless a toxic substrate is fed to the biore-
           actors.




               Raw materials

                 Milling &
                size reduction
                     Large polymer structures
               Pretreatment or
                liquefaction
                     Small polymers
                Hydrolysis or  Solid residuals
               saccharification
                     Sugar solution
               Detoxification



                Fermentation  Yeast
                     Fermented solution
                 Distillation            Ethanol (~90–95%)


               Soild separation,
             evaporation, drying           Dehydration

              Dried   Wastewater          Ethanol (>99%)
           by-products
           Figure 3.3 A general process scheme for ethanol production
           from different raw materials.
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