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76                           Biomass Gasification, Pyrolysis and Torrefaction


            content of biomass is generally very small but may play a significant role in
            biomass utilization especially if it contains alkali metals such as potassium
            or halides such as chlorine. Straw, grasses, and demolition wood are particu-
            larly susceptible to this problem. These components can lead to serious
            agglomeration, fouling, and corrosion in boilers or gasifiers (Mettanant et al.,
            2009).
               The ash obtained from biomass conversion does not necessarily come
            entirely from the biomass itself. For collection, biomass is often scraped off
            the forest floor and then undergoes multiple handlings, during which it can
            pick up a considerable amount of dirt, rock, and other impurities. In many
            plants, these impurities constitute the major inorganic component of the
            biomass feedstock.


            3.6.2.3 Moisture
            High moisture is a major characteristic of biomass. The root of a plant bio-
            mass absorbs moisture from the ground and pushes it into the sapwood. The
            moisture travels to the leaves through the capillary passages. Photosynthesis
            reactions in the leaves use some of it, and the rest is released to the atmo-
            sphere through transpiration. For this reason, there is more moisture in the
            leaves than in the tree trunk.
               The total moisture content of some biomass can be as high as 90% (db),
            as seen in Table 3.12. Moisture drains much of the deliverable energy from a
            gasification plant, as the energy used in evaporation is not recovered. This
            important input parameter for design must be known for assessment of the
            cost of transportation or energy penalty in drying the biomass. The moisture
            in biomass can remain in two forms: (1) free or external and (2) inherent or
            equilibrium.
               Free moisture is that which is above the equilibrium moisture content. It
            generally resides outside the cell walls. Inherent moisture, on the other hand,
            is absorbed within the cell walls. When the walls are completely saturated,
            the biomass is said to have reached the fiber saturation point or equilibrium
            moisture. Equilibrium moisture is a strong function of the relative humidity




              TABLE 3.12 Typical Moisture Content of Some Biomass
                                         Dairy
                     Corn  Wheat Rice  Rice Cattle  Wood   Food RDF  Water
                     Stalks Straw  Straw Husk Manure Bark  Sawdust Waste Pellets Hyacinth
              Moisture  40 60 8 20  50 80 7 10 88  30 60 25 55  70  25 35 95.3
              (wet basis)
              Source: Compiled from Kitani and Hall (1989, p. 863).Biomass
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