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330    Cha pte r  Ele v e n

               Blow Molding  The blow molding process involves blowing into a
               molten thermoplastic tube with high-pressure air to conform to the
               shape of a cooled mold. Air or nitrogen gas is introduced into the
               tube causing the molten mass to expand against the walls of the mold
               where it solidifies on cooling. The mold is then opened to remove the
               container. There are three common types of blow molding: extrusion
               blow molding, injection blow molding, and injection stretch blow
               molding.  1,2,6
                   In extrusion blow molding, the polymer melt is extruded through
               a die as a hollow tube, known as a parison. The chilled split mold
               arranged around the parison is then closed. Air is blown through a
               blow pin mounted inside the die head that blows the parison into the
               final container shape (Fig. 11.4). Extrusion blow molding is used with
               HDPE, PP, and polyvinyl chloride (PVC). Some of these polymers are
               coextruded with ethylene vinyl alcohol (EVOH) or nylon to provide
               desired barrier properties at an economical price. Injection molding is
               a two-step process for making a container. At first stage, a molten
               plastic is injection molded into a thick hollow tube known as preform
               and then preform is transferred to a second mold where blowing with
               compressed air forms the final shape (Fig. 11.5). This process is virtu-
               ally scrap free and no further trimming is required of the finished
               containers. Compared to extrusion blow molding, the tooling cost of
               this process is higher and is typically limited to the production of
               relatively small bottles. The most common polymers for injection
               blow molding are LDPE, HDPE, PP, PS, PVC, and PET. Injection
               stretch blow molding is an extension of injection blow molding where
               containers with orientation in both longitudinal and transverse direc-
               tions are produced. A stretch rod is used to stretch the preform in the


                                       Extruder die





                               Blades           Air
                Blow pin
           Parison


            Mold



                     Extrusion of     Blowing air       Finished container
                    polymer melt      and cooling           release
          FIGURE 11.4  Extrusion-blown molding. (Adapted from Ref. 2.)
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