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Residence Times of Silicic Magmas Associated with Calderas             3


             volcanism is the topographical depressions left after the eruption. These are thought
             to be the result of either tremendous explosions that blew apart a pre-existing
             volcanic cone or due to subsidence of the roof of the reservoir after or during
             magma evacuation. High-level magma emplacement (typically o10 km depth)
             seems to be required for caldera formation, but when combined with the apparent
             large size of some reservoirs, questions arise as to the thermal and mechanical states
             of the crust and the magma, the rates and mechanisms of vapour- and silica-rich
             magma differentiation, and the timescales of transport and storage of huge
             quantities of eruptible silicic magma (e.g., Smith, 1979; Hildreth, 1981; Shaw 1985;
             Jellinek and DePaolo, 2003). These issues were addressed by Shaw (1985) who
             noted that ‘‘the interaction of magma generation rates, stress domains and injection
             rates leads to a spectrum of residence times which effectively determine the
             types of intrusive and volcanic suites seen at high crustal levels and at the surface.’’
             Almost 25 years later, progress in analytical techniques have enabled the
             quantification of the time over which crystals and magma are stored before a
             caldera-forming eruption. This allows analysing the relations between the volumes,
             compositions, temperatures and depths of magma reservoirs below calderas from a
             new perspective. The purpose of this manuscript is to describe the approaches used
             to obtain the time scales of magmatic processes, to compile the data on residence
             times of major caldera-related complexes, and to use this information for deriving
             modes and rates of silica-rich magma production and storage in the Earth’s crust.


             1.1. What is the residence time of a magma?
             It can be defined as the time elapsed since the magma was formed and its eruption.
             Uncertainties arise with the meaning of ‘when’ a magma is formed because what
             is finally erupted is a mixture of phases that might have very different origins in
             time and space (e.g., Bacon and Lowenstern, 2005). The most widespread use of
             residence time involves pinpointing when a given mineral started to crystallise,
             presumably during storage in a magma reservoir. This is different from the
             definition used in oceanic geochemistry or in highly active volcanic systems where
             it refers to the (mean) time that a given element or isotope spends in a reservoir
             before being removed (e.g., Holland, 1978; Albare `de, 1993). In practice, one can
             calculate the residence time as the difference between the eruption age as obtained
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             by K–Ar (or  40 Ar/ Ar), (U, Th)/He and  14 C methods (for prehistorical eruptions)
             and the age provided by other radioactive clocks, such as Rb–Sr, and U–Th–Pb.
             From this definition it is apparent that the residence time does not need to be a
             single value, and might depend on the phases and radioactive isotopes that are used.
             Multiple values of residence times may arise from different crystallisation ages of
             different minerals, but also from the fact that the very definition of an age requires
             knowledge of when the radioactive system became closed. This condition depends
             on several factors but strongly on the diffusion rate of the daughter isotope, and
             has been quantified with the use of a closure temperature (Dodson, 1973). This
             explains the a priori paradoxical situation that, for example, a sanidine might
             have two different ages and both could be correct: dated by the K–Ar system the
             mineral gives the eruption age but using Rb–Sr clock it may give a much older
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