Page 198 - Chalcogenide Glasses for Infrared Optics
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174   Cha pte r  Se v e n


                              Monitor cure: DEFT self-priming topcoat
                        On application



                     Absorbance







                        Fully cured
                         3500    3000    2500    2000    1500
                                                 –1
                                     Wavenumber (cm )
              FIGURE 7.16  Cure of a urethane paint as measured by the Semsiv IR
              refl ectance probe. The example shows how the probe can be used to monitor
              the cure of a coating after its application. This is a urethane paint system,
              and the curing reaction is followed by the decrease in absorbance of the
              isocyanate functionality.


              substantial energy from the CW CO laser. The main application of
              AMI IR glass fibers has been chemical analysis and chemical reaction
              studies. Measurements of this kind were not possible before the
              development of both the FTIR spectrophotometers and chalcogenide
              glass fibers covering the wavelength ranges used in analysis. For
              AMI, IR fibers have been a small but continuous business since the
              beginning in 1990. Never has this activity been a large portion of total
              sales, but AMI considers this activity important.


        7.4  Extrusion of Chalcogenide Glasses
              AMI became involved in the extrusion of chalcogenide glasses in an
              unusual manner. In late spring of 1993, we had a visit from Jacob
              Fraden, founder of the company Thermoscan. He had developed an
              electronic device to measure a person’s temperature from the infra-
              red emission of the tympanic membrane of the ear. Figure 7.17 shows
              the device as advertised by Dillards in the Dallas Morning News in
              1992. The main market thrust was for use with infants and small chil-
              dren. Sales were already in the thousands. The purpose of Jacob
              Fraden’s visit was to see if we could produce small, inexpensive
              infrared glass light pipes to replace the light pipe in current use.
              When a company has a device being sold on the market in quantities
              of thousands a month, reduction in cost by $1 or $2 of a single
              element used in its construction leads to a substantial increase in
              profit. The current light pipe was a short piece of copper tubing that
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