Page 11 - Characterization and Properties of Petroleum Fractions
P. 11

P2: IML/FFX
                                        T1: IML
  P1: IML/FFX
                           QC: IML/FFX
            AT029-Manual
                         AT029-Manual-v8.cls
                                           June 19, 2007
  AT029-FM
         x CONTENTS
                                    4.8 Calculation of Properties of Crude Oils and
                                        Reservoir Fluids  16:4                               189
                                         4.8.1 General Approach                              190
                                         4.8.2 Estimation of Sulfur Content of a Crude Oil   191
                                    4.9 Conclusions and Recommendations                      192
                                   4.10 Problems                                             193
                                        References                                           194
                        Chapter 5—PVT Relations and Equations of State                       197
                                        Nomenclature                                         197
                                    5.1 Basic Definitions and the Phase Rule                  198
                                    5.2 PVT Relations                                        199
                                    5.3 Intermolecular Forces                                202
                                    5.4 Equations of State                                   203
                                         5.4.1 Ideal Gas Law                                 203
                                         5.4.2 Real Gases—Liquids                            203
                                    5.5 Cubic Equations of State                             204
                                         5.5.1 Four Common Cubic Equations (vdW, RK,
                                               SRK, and PR)                                  204
                                         5.5.2 Solution of Cubic Equations of State          206
                                         5.5.3 Volume Translation                            207
                                         5.5.4 Other Types of Cubic Equations of State       208
                                         5.5.5 Application to Mixtures                       209
                                    5.6 Noncubic Equations of State                          210
                                         5.6.1 Virial Equation of State                      210
                                         5.6.2 Modified Benedict–Webb–Rubin Equation
                                               of State                                      214
                                         5.6.3 Carnahan–Starling Equation of State and Its
                                               Modifications                                  214
                                    5.7 Corresponding State Correlations                     215
                                    5.8 Generalized Correlation for PVT Properties of
                                        Liquids—Rackett Equation                             222
                                         5.8.1 Rackett Equation for Pure Component
                                               Saturated Liquids                             222
                                         5.8.2 Defined Liquid Mixtures and Petroleum
                                               Fractions                                     223
                                         5.8.3 Effect of Pressure on Liquid Density          223
                                    5.9 Refractive Index Based Equation of State             225
                                   5.10 Summary and Conclusions                              227
                                   5.11 Problems                                             228
                                        References                                           229

                        Chapter 6—Thermodynamic Relations for Property Estimations           232
                                        Nomenclature                                         232
                                    6.1 Definitions and Fundamental Thermodynamic
                                        Relations                                            234
                                         6.1.1 Thermodynamic Properties and
                                               Fundamental Relations                         234
                                         6.1.2 Measurable Properties                         235
                                         6.1.3 Residual Properties and Departure
                                               Functions                                     236
                                         6.1.4 Fugacity and Fugacity Coefficient for Pure
                                               Components                                    237
                                         6.1.5 General Approach for Property Estimation      238
                                    6.2 Generalized Correlations for Calculation of
                                        Thermodynamic Properties                             238




           --`,```,`,``````,`,````,```,,-`-`,,`,,`,`,,`---









   Copyright ASTM International
   Provided by IHS Markit under license with ASTM             Licensee=International Dealers Demo/2222333001, User=Anggiansah, Erick
   No reproduction or networking permitted without license from IHS  Not for Resale, 08/26/2021 21:56:35 MDT
   6   7   8   9   10   11   12   13   14   15   16