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120 SECTION    II Types of Equipment























            FIG. 3.82 Simplified hydrodesulferization process [31].


            ammonia, water, and hydrogen chloride. Unfortunately, these products can have
            further reactions to form various salt compounds that can condense and deposit
            onto surfaces. The reactor effluent is cooled and flows through a series of gas/
            liquid separators. In this example, a steam stripper removes gas and naphtha
            leaving low sulfur product.
               The gas from the final separator flows to a hydrogen sulfide (H 2 S) scrubber
            where liquid amines are used to remove the H 2 S from the recycle gas. Gas
            from the scrubber enters the inlet of the recycle compressor. Since hydrogen
            is consumed by the chemical reactions, a makeup compressor supplies addi-
            tional hydrogen to the loop. This compressor is typically a reciprocating unit.
            The gas entering the compressor is primarily hydrogen plus additional
            hydrocarbons.
               Some design challenges for a hydrogen compressor include the following:
            l High pressure—up to 17.3MPa.
            l Rotordynamic considerations—the low molecular weight of hydrogen recy-
               cle gas demands many stages (a long rotor) and high rotational speeds for
               just a moderate pressure rise.
            l Fouling from salts.
            A hydrogen recycle compressor is shown in Fig. 3.83. This compressor has 11
            stages of compression. The rated discharge pressure is 11.00MPa. The maxi-
            mum continuous speed is 14,051rpm.


            Air/Nitrogen

            Centrifugal compressors are also used for plant air compression and in air sep-
            aration applications. In air separation, nitrogen and oxygen are separated from
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