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CHARACTERIZATION OF HALF-TONE PRINTERS                 149
             fibres to which the dyes are applied. The application of the Kubelka–Munk
             theory to opaque dyed textiles is therefore often referred to as the one-constant
             version of the theory. For many pigmented surface coatings, such as paints, the
             pigments both absorb and scatter and the two-constant theory is required.
             However, Equation (9.12) can still be used to predict the reflectance of the
             surface coating if it is applied at a thickness that achieves opacity. For
             translucent printing inks, however, the reflectance of the paper upon which the
             ink is printed makes a contribution to the reflectance of the system and therefore
             Equation (9.12) must be replaced by
                  R ¼½ðR g   R 1 Þ=R 1  ðR 1 R g   1Þ expfð1=R 1   R 1 ÞSxgŠ=
                      ½ðR g   R 1 Þ ðR g   1=R 1 Þ expfð1=R 1   R 1 ÞSxgŠ,     ð9:13Þ


             where R is the reflectance of the substrate and R 1 is the reflectance [as defined
                    g
             by Equation (9.12)] of an opaque layer of the pigmented layer. The scattering
             coefficient S is defined for a unit thickness of the layer and x is the thickness of
             the layer. According to the theory the values of K and S should be linearly
             related to the pigment volume concentration in the layer and to the thickness of
             the layer. However, in practice severe departures from linearity can occur
             (Nobbs, 1997). In order to predict the reflectance for a mixture of colorants or
             inks the K and S contributions are determined for each component and then
             assumed to be additive in order to allow the computation of K and S for the layer
             and thus, via Equation (9.13), the reflectance R. In all cases, once the body
             reflectance is known Equation (9.11) can be used to yield a prediction of the
             reflectance P.
               The Kubelka–Munk theory is routinely used for the prediction of reflectance
             for systems of printing inks (for example, in lithography) and forms the basis of
             computer match-prediction systems. However, one of the difficulties in applying
             the theory to the characterization of printers is in determining the values of K
             and S for the individual inks. One method to determine K and S is to print each
             colorant over two different substrates or papers (for example, a white and a
             black) and then to use Equation (9.13) to set up a system of two simultaneous
             equations with two variables (K and S). For many printing systems it is difficult
             to obtain these samples, especially since it is required that the surface properties
             (roughness, etc.) of the two substrates must be identical. An alternative approach
             is to treat the Kubelka–Munk coefficients as free parameters and to derive their
             values based on an optimization routine and a set of samples of known
             reflectance (Bala, 2003).
               The Kubelka–Munk model could be used to predict the overlap areas in a
             half-tone printing process and Neugebauer-type models could then be used to
             predict the reflectance of a given area. The traditional Kubelka–Munk theory
             assumes that the printed layer is homogeneous, however, whereas for half-tone
             printing one ink is printed on top of another to generate a more layered
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