Page 408 - Corrosion Engineering Principles and Practice
P. 408

376   C h a p t e r   9                              A t m o s p h e r i c   C o r r o s i o n    377



                       Material             Urban industrial †  Rural ‡  Marine §
                       T.P. copper               1.42        0.58     1.45
                       Phosphor bronze           1.91        0.56     2.51
                       Red brass                 1.80        0.51     0.58
                       Yellow brass              2.16        0.58     0.46
                       90–10 Cupro Ni            3.78        2.08     2.90
                       Tin brass                 1.73        0.76     0.61
                       Admiralty metal           2.51        0.51     0.33
                       Manganese bronze          8.64        0.48     2.02
                       Si Al bronze              1.27        0.33     0.33
                       10% Ni silver             1.96        0.64     0.58
                       18% Ni silver             2.01        0.61     0.53
                       Advance                   1.55        0.25     0.46
                       Be copper                 1.75        0.76     1.02
                       12 different coppers      0.81        0.46     1.35

                      †   Newark, N.J.
                      ‡   State College, Pa.
                      §   Kure Beach, N.J.; La Jolla, Calif.
                      TABLE 9.6  Corrosion of Copper and Copper Alloys in mm/y



                      The results shown in Table 9.7 were obtained for several representative
                      alloys. As can be concluded from these data, nickel tends to be passive in
                      a  marine  atmosphere.  The  ratio  between  the  corrosion  rate  for  nickel
                      exposed to the industrial atmosphere and that exposed to rural or marine
                      atmospheres was 28:1.
                      9.7.4  Aluminum and Aluminum Alloys
                      Aluminum, in its many forms is exceeded only by steel in tonnage
                      directly exposed to the elements. It is produced in the form of wrought
                      products,  extrusions,  and  castings  with  a  large  variety  of  alloying
                      elements to impart desired mechanical properties. Before anodizing*,
                      the atmospheric corrosion behavior of aluminum products fits into
                      some fairly well-defined patterns that are related to composition.
                         While  pure  aluminum  has  excellent  atmospheric  corrosion
                      resistance and is used extensively as a cladding materials for this very


                      * See Chap. 5 for a detailed description of aluminum anodizing and Chap. 4 for a
                       description of the thermodynamic corrosion stability of pure aluminum.
   403   404   405   406   407   408   409   410   411   412   413