Page 700 - Corrosion Engineering Principles and Practice
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654     C h a p t e r   1 4                                                                                                        P r o t e c t i v e   C o a t i n g s    655


                      of the coating and the manufacturer of the holiday detector. ASTM
                      G62-07 Standard describes two test methods for holiday detection in
                      pipeline coatings.
                         ASTM G62-0 Method A is designed to detect holidays such as pin-
                      holes and voids in thin-film coatings from 0.0254 to 0.254 mm in thick-
                      ness  using  ordinary  tap  water  and  an  applied  voltage  of  less  than
                      100 V DC. This method is effective on films up to 0.508 mm thickness
                      if a wetting agent is used with the water and may be considered to be
                      a non-destructive test because of the relatively low voltage. But Meth-
                      od A will not detect thin spots in the coating, even those as thin as
                      0.635 mm. However, this can be achieved with ASTM G62-07 Method
                      B because of the higher applied voltages, between 900 and 20000 V
                      DC.  Method  B  is  considered  destructive  because  the  high  voltages
                      involved generally destroy the coating at thin spots.

                 14.10  Surface Preparation

                      Surface preparation is a critical part of coating projects and must provide
                      a surface that is compatible with the coating material to be applied. The
                      main concerns in this aspect of protective coatings are the cleanliness of
                      the surface required and the surface roughness or profile that essentially
                      provide  anchorage  to  the  coating.  It  is  believed  that,  of  the  cost  of
                      a coating  job,  as  much  as  one-half  to  two  thirds  goes  for  surface
                      preparation and labor.
                         In some cases it is impossible to provide the best prepared surface
                      because there is insufficient money or time to do the job and/or it is
                      not permitted because of possible product contamination, fire hazard,
                      or some other reason. It must however be recognized that when there
                      is a lesser surface preparation, the longevity of a coating system will
                      likely be compromised.
                         The  surface  properties  of  the  substrate  to  which  a  coating  is
                      applied will influence its performance. Surfaces in compression often
                      increase coating performance because they tend to be attacked less
                      than surfaces that are less stressed; on the other hand, surfaces in
                      tension may cause coatings to fail earlier than they would otherwise.
                      Differences  in  expansion  rates  between  a  coating  and  a  substrate
                      impose stresses on the coating which may lead to cracking and failure.
                      Additionally, both inadequate and excessive coating thickness may
                      lead to failure.

                      14.10.1  Principles of Coating Adhesion
                      Of the cleaning methods available to provide the cleanest and largest
                      effective surface per unit area, the use of abrasive blasting produces
                      a surface closest to the ideal surface profile. However, the best of
                      blasted surfaces can still be badly contaminated with residual metal
                      oxides,  extraneous  dirt,  particles  of  the  abrasive  materials,  and
                      adsorbed gases on the metal. As a consequence, it is necessary to
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