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56  Chapter 3 Design Philosophies
                 of the potential for fire by installing a sprinkler system on the tank, and the removal
                 of any adjacent fire source formed part of the solution. Additional solutions included
                 the elimination of all other potential pressure increases by installing instrumental
                 protection with appropriate precautions and in-process relief.

                                    Quench

                                        Vent
                                                            P







                    NH3
                                                        NH3
                                   WASTE TANK


                 Pressure relieve with quench     Instrumental protection with
                 water absorber and waste tank     sprinkler system no waste

                 Fig. 3.5. NH 3 storage with recovery system versus a simple
                 instrumental protection system.



                 3.3.10.2  Design for first-pass prime production
                The design of first-pass prime (Aelion and Powers, 1991; Verwijs et al., 1995) is a
                 concept that has not yet been extensively explored, though it has the same objective
                 as ªprevent versus cureº. The concept is to avoid expensive provisions in plants in
                 order to cope with off-specification products that have originated from the start or
                 recovery of a facility. A careful design of start-up and standby procedures is required
                 to achieve the objective of first-pass prime production, see Chapter 8. Therefore, it is
                 important to distinguish between process units as being reversible or irreversible.
                   A reversible unit operation is defined (Verwijs et al., 1995) as: ªA process system
                 that can be operated stand alone without any process stream fed in or out of the
                 system, due to the presence of inverse operationsº. This yields the possibility of con-
                 ditioning a process system during an operational state of the process. Irreversible
                 unit operations can only be operated by supplying an appropriate feed.
                   Automated plants have defined process states. Next to the actual production state,
                 transient steps are defined for start-up, shutdown, and product changes. Process
                 wait states, also called standby, are also introduced, which have defined process con-
                 ditions, before the process is moved to another operational state. Process wait states
                 can be differentiated in:

                   .  Cold process wait condition (cold standby): at this state the inventory in the
                      units is established.
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