Page 75 - Design of Simple and Robust Process Plants
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3.3 Design Philosophies  59



                   Sprinkler
                                Inert                       Vent recovery
                   Vapor return
                                 H                         HH
                                   P                     P
                            A    L           A             LL
                                               O2
                             HC                               HH
                                                            L
                                                              LL
                                       H           HH
                                H
                  Loading F   T        L  T      T  LL      L  H
                           L    L            A                L
                                               H2O         L  H  H    H
                                                               P   T
                                                                 L    L
                     Heating system
                                                  Maximum          Feed to plant
                                                  flow valve    H      H
                                                              P     T
                                                                L      L
                 Fig. 3.6. Safety provisions of a storage tank for product X.

                   Some basic questions for storage tank designs from an inherently safer design
                 perspective based on the four guiding words are:

                 Minimize
                   .  Do we really need the tank? Could product X be supplied by pipeline?
                   .  Can we avoid storage and handling by direct feeding from process to pro-
                      cess?
                   .  Did we consider feeding to the process in the gas phase (less inventory of
                      toxic material)?
                   .  Did we consider a smaller tank?
                   .  Did we consider buying in containers to avoid handling and feed on pressure
                      into the process?

                 Substitute
                   .  Do we really need this chemical?
                   .  Could we replace it with a less harmful product?
                 Consider the effects of vapor pressure, toxicity, flammability, reactivity, inter-reactiv-
                 ity with other plant components, solidification point, product degradation. All these
                 properties add to the safety provisions.


                 Moderate
                   .  Do we really need the chemical in the form as it is?
                   .  Can it be handled in a less harmful form? For example in dilute solution,
                      another phase, mixing with another inert material. You might consider low-
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