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wavelength  dispersion  (in  x-ray  emission  formofaboundaryvalueproblemisthroughinte-
                 spectroscopy) Spatial separation of characteristic  gration by parts, using Green’s formulas.
                 x-rays according to their wavelengths.
                                                           wedge projection  A stereochemical projec-
                 wavelength-dispersive  x-ray  fluorescence  tion, roughly in the mean plane of the molecule,
                 analysis  A  kind  of  x-ray  fluorescence
                                                           in which bonds are represented by open wedges,
                 analysis  involving  the  measurement  of  the
                                                           tapering off from the nearer atom to the farther
                 wavelength  spectrum  of  the  emitted  radiation
                                                           atom.
                 e.g., by using a diffraction grating or crystal.
                                                           Weierstrass theorem  See Bolzano-Weier-
                 wavelength error (in spectrochemical analysis)
                                                           strass theorem.
                 The error in absorbance which may occur if there
                 is a difference between the (mean) wavelength
                 of the radiation entering the sample cell and the  weight, G G G  Force of gravity acting on a body,
                 indicated wavelength on the spectrometer scale.  G = mg, where m is its mass and g the acceler-
                                                           ation of free fall.
                                                  2
                                                     n
                 wavelet   An  orthonormal  basis  of  L (R ).
                 They are used as phase space localization meth-
                                                           weighted mean   If in a series of observations
                 ods.  A typical example of a family of wavelets
                                                           a statistical weight (w ) is assigned to each value,
                                                                            i
                 ψ (x) in one dimension is given by        a weighted mean x w  can be calculated by the
                  j,k
                                                           formula
                                  −j/2
                                        −j
                        ψ (x) = 2    ψ(2 x − k)                                 w x
                          j,k
                                                                        x =     w i i
                                                                         w
                                    j
                           −j  x − 2 k                                            i
                        = 2 2 ψ(   j  ), j, k ∈ Z,
                                  2                          Comment: Unless the weights can be assigned
                                                           objectively, the use of the weighted mean is not
                 where ψ  is a smooth function with reasonable
                 decay  (say,  |ψ(x)| < C(1 + |x|) −(1+") ),  and  normally recommended.

                 such that ψ(x)dx = 0. Wavelets bases provide
                 unconditional bases for many classical function  well-ordered set  A partially ordered set
                               p
                 spaces, such as L spaces 1 < p < ∞, Sobolev  (A,  ) such that for all B ⊂ A (B non-empty)
                                                      s
                        s
                 spaces W , Besov spaces B q p,s , H¨older spaces C ,  B has a minimum.
                             1
                 Hardy space H , and BMO space.
                                                           well posed  Most people mean that the math-
                 wavelet  transformations  Approximations  ematical program has an optimal solution. Some
                 that can have lower complexity than fast Fourier
                                                           mean just that it is feasible and not unbounded.
                 transforms (FFT), namely, O(log N) instead of
                 O(N log N).
                                                           wet bulb temperature  In psychrometry, the
                                                           temperature of the sensor or the bulb of a ther-
                 weak  collision  A  collision  between  two
                                                           mometer in which a constantly renewed film of
                 molecules in which the amount of energy trans-
                                                           water is evaporating. The temperature of the
                 ferred from one to the other is not large compared
                                                           water used to renew the film must be at the tem-
                 to k T  (k is the Boltzmann constant and T  the
                        B
                    B
                 absolute temperature). See strong collision.  perature of the gas.
                 weak formulation   To cast a boundary value  wetting tension (or work of immersional wet-
                 problem for a partial differential operator into  ting per unit area)  The work done on a
                 weak form means that it is stated as a variational  system when the process of immersional wet-
                 problem over some Banach space V .  The usual  ting involving unit area of phase β is carried out
                 way to get this weak formulation from the strong  reversibly:
           © 2003 by CRC Press LLC
           © 2003 by CRC Press LLC
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