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            0521820928c05  CB644-Petlyuk-v1                                                      June 11, 2004  20:15





                        144    Distillation Trajectories and Conditions of Mixture Separability

                                                  2
                                         a)




                                             x D
                                                +
                                              N
                                       1                       4
                                           x  t
                                            rev                   Figure 5.25. The evolution of separatrix tra-
                                                                  jectory bundle and separatrix sharp split re-
                                                                                  4
                                                                       1
                                                                            +
                                               3                  gion S → N ≡ Reg sh,R  of the rectifying sec-
                                                                                  sep,r
                                                                                 1,2,3
                                                                  tion for an ideal mixture with K 1 > K 2 > K 3 >
                                                  2               K 4 (mixture 1,2,3 is the product): (a) L/V <
                                    D
                                         b)                       (L/V) t rev , (b) L/V > (L/V) t rev .(L/V) t rev , val-
                               F                                  ues of L/V at reversible-distillation trajectoriy
                                                                  tear-off point from the face 1-2-3.
                                    B
                                             x D
                                                        +
                                                       N
                                       1                       4
                                             S  1


                                               3




                            D
                                      2                      3  2                    S  3  2
                              a)                       b)   S                  c)
                       F         α
                                  23                       α                       α
                                                            23                      23
                            B
                              2                            2
                             S                            S
                                1234      1324
                           x       +                 x D              +      x                  +
                            D     N       α                          N        D            α  N
                           1               23    4  1                     4  1              23     4
                            −                        −                        −
                           N                        N                        N
                            S 3 (1)                    3
                                α                     S  (1)  α                   α 23
                                 23
                                                           23
                                   3                        3                     S 2  3
                                                                      2,3,4
                               Figure 5.26. The evolution of trajectory regions, Reg R  ≡ Reg 1  of the rectifying section
                                                                        w,r    att
                                                                       1
                               (hatched and shaded) for an mixture with α 23 surface (component 1 is the product):
                                             1
                                                 1
                                        1
                               (a) L/V > K > K > K , (b) L/V > K 2 at point α 23 on side 1-2, (c) L/V > K 2 at point α 23 on
                                             3
                                                 4
                                        2
                                                             3,4    2,4
                                                               t
                                                                      t
                               side 1-3. Double line, tear-off segments Reg and Reg .
                                                                      r
                                                               r
                                                             1,2    1,3
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