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Chapter 7 – DRILLING FLUIDS                                      161






                    Solids-free brines

                    Brines are used when working within the reservoir so as to minimize

                 damage to the formation that would slow down the flow of oil or gas to the
                 well. Sometimes a solids-free or a brine system is used for drilling through
                 the reservoir. Later on during completion or workover operations, these
                 systems are again useful to reduce or eliminate damage. (As previously
                 discussed, a workover is the process of repairing damage to a well, often
                 by removing the completion and running a new one.)
                    Brines can be formulated as solids-free systems with density gradients
                 up to 1.07 psi/ft (2.47 SG). Solids weighting materials and fluid loss additives

                 that are acid soluble can also be added, such as calcium carbonate and iron
                 carbonate. While being able to overbalance formation pressures, properly
                 designed brines do not create formation damage, whether by plugging the
                 reservoir with irremovable solids or by causing reactions with formation

                 fluids or solids. Potential interactions of brines in the reservoir include
                 the following:
                        ▪ Scale from the reaction of a divalent brine with dissolved carbon
                        dioxide, producing an insoluble carbonate. (Divalent brines are
                        those containing calcium or zinc salts.)
                        ▪ Precipitation of sodium chloride from the formation water when it
                        is exposed to certain brines.
                        ▪ Precipitation of iron compounds in the formation resulting
                        from interaction with soluble iron in the completion fluid (most

                        common with zinc bromide, ZnBr ).
                                                        2
                        ▪ Reaction of formation clays with the brine.
                        ▪ Corrosion of casings and tubulars.



                    Oil muds and invert oil emulsion muds

                    An oil mud is comprised of various solids and additives mixed into
                 an all-oil continuous phase, with little or no water (10% or less by volume
                 of liquid).
                    With an invert oil emulsion mud, water is present at more than 10% by
                 volume within the continuous oil phase as an emulsion. The water (brine
                 would be more accurate because it will contain dissolved salts) forms tiny






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