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(3.61)and writing the derivatives in Cartesian coordinates we obtain

                                   1                        1       1       2  1
                                              1





                            (r) =       ρ(r )       + (r ·∇ )     + (r ·∇ )       +· · · dV .  (3.90)
                                  4π	  V      R    r =0     R    r =0  2     R    r =0



                        For the second term we can use (3.57)to write

                                                                        ˆ
                                                          1             R            ˆ r
                                           1





                                     (r ·∇ )     = r · ∇         = r ·          = r ·  .       (3.91)
                                           R    r =0      R    r =0     R 2    r =0  r 2



                        The third term is complicated. Let us denote (x, y, z) by (x 1 , x 2 , x 3 ) and perform an
                        expansion in rectangular coordinates:
                                                               3
                                                            3
                                                           
 
         ∂ 2
                                                   2
                                            (r ·∇ )  1      =    x x j     1      .


                                                                  i
                                                   R                 ∂x ∂x R


                                                     r =0  i=1 j=1     i  j  r =0


                        It turns out [172] that this can be written as

                                                             1            2 ¯
                                                     2
                                                     1

                                             (r ·∇ )       =   ˆ r · (3r r − r I) · ˆ r.

                                                     R       r 3
                                                       r =0

                        Substitution into (3.90)gives
                                                                       ¯
                                                     Q     ˆ r · p  1 ˆ r · Q · ˆ r
                                             (r) =      +       +          +· · · ,            (3.92)
                                                   4π	r   4π	r  2  2 4π	r  3
                        which is the multipole expansion for  (r). It converges for all r > r m where r m is the
                        radius of the smallest sphere completely containing the charge centered at r = 0 (Figure

                                                     ¯
                        3.11). In (3.92) the terms  Q, p, Q, and so on are called the multipole moments of ρ(r).
                        The first moment is merely the total charge



                                                       Q =   ρ(r ) dV .
                                                            V
                        The second moment is the electric dipole moment vector




                                                      p =   r ρ(r ) dV .
                                                           V
                        The third moment is the electric quadrupole moment dyadic

                                                  ¯              2 ¯
                                                 Q =    (3r r − r I)ρ(r ) dV .
                                                       V
                          The expansion (3.92)allows us to identify the dominant power of r for r   r m .
                        The first nonzero term in (3.92)dominates the potential at points far from the source.
                        Interestingly, the first nonvanishing moment is independent of the location of the origin
                        of r , while all subsequent higher moments depend on the location of the origin [91]. We

                        can see this most easily through a few simple examples.
                          For a single point charge q located at r 0 we can write ρ(r) = qδ(r − r 0 ). The first
                        moment of ρ is



                                                  Q =    qδ(r − r 0 ) dV = q.
                                                        V
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