Page 88 - Elements of Chemical Reaction Engineering 3rd Edition
P. 88

60                                 Conversion and Reactor Sizing   Chap. 2

                               2. For the reaction
                                                          b          d
                                                      A+-        c+- D
                                                          a    a     a
                                  The relative rates of reaction can be written either as





                                                              or                       (S2-1)





                               3. The conversion X is the moles of A reacted per mole of  A feed.

                                               For batch systems:   X=  NAO  - NA      (S2-2)
                                                                          NAO

                                               For flow systems:   x=- FAO - FA        (S2-3)
                                                                          FA0
                               4. For reactors in series with no side streams or multiple feeds, the eval-
                                 uation of the design equations may be simplified by letting the conver-
                                 sion represent  the  total  moles  reacted  up  to  a particular  point  in  the
                                 series of reactors.
                               5. In  terms  of  the  conversion,  the  differential  and  integral  forms of  the
                                 reactor design equations become:


                                         Differential Form   Algebraic  Form   Integral  Form









                                 CSTR

                                            dX
                                 PER     F  -=-r
                                          AodV    A
                                 PBR     F   dX
                                            -=-TI
                                          AodW     A

                               6. If  the rate  of disappearance  is given  as a function  of  conversion, the
                                 following  graphical  techniques  can  be  used  to  size  a  CSTR  and  a
                                 plug-flow reactor.
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