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 Encyclopedia of Physical Science and Technology  En006G-249  June 27, 2001  14:7








              Fluid Dynamics (Chemical Engineering)                                                        51

                                                                simply to the statement that mass flow or volume flow is
                                                                constant,

                                                                              v  1 A 1 = v  2 A 2 = Q,    (49)
                                                                where Q is the volume flow. This relation defines the area
                                                                mean velocity as Q/A. Equation (49) is the working form
                                                                most often used.

                                                                B. Momentum Balance
              FIGURE 1 Schematic illustration of notation used in developing
              macroscopic equations.                            Settingψ equaltoρvinEq.(46)producesthemacroscopic
                                                                momentum balance. The term  j Dψ · n  w represents the
              III. BASIC FIELD EQUATIONS                        reaction force of the wall of the pipe on the fluid arising
                 (AVERAGED OR MACROSCOPIC)                      from friction and changes in the direction of flow. The
                                                                     ˙
                                                                term R ψ V represents the action of the body force ρg on
              While the differential equations presented here are general  the total flow. Thus, Eq. (46) becomes
              and can be used to solve all types of fluid mechanics prob-
                                                                   ∂M
              lems, to the average “practical” chemical engineer they  =−ρ vv · n  1 A 1 − ρ vv · n  2 A 2 − pn  1 A 1
                                                                   ∂t
              are often unintelligible and intimidating. Much more fa-
              miliar to most engineers are the averaged or macroscopic   − pn  2 A 2 + F w + ρV g,        (50)
              forms of these equations.
                                                                where M is the total momentum of the flow. Equation (50)
                Equation (1) contains the integral form of the general
                                                                can be solved at steady state for the reaction force F w as
              balance relation. In this form it is a Eulerian result. If
              we take the volume in question to be the entire volume
                                                                      F w = pn  1 A 1 + pn  2 A 2 + ρ vv · n  1 A 1
              of the pipe located between two planes located at points
              1 and 2 separated by some finite distance, as shown in         + ρ vv · n  2 A 2 − ρV g.     (51)
              Fig. 1, Eq. (1) can be written in the following a verage or
                                                                As an illustration of the use of this result, consider the
              macroscopic form,
                                                                pipe bend shown schematically in Fig. 2. Presuming the
              ∂                                                 pipe to lie entirely in the x–y plane, we compute F wx =
                 =− ψv · n  2 A 2 − ψv · n  1 A 1 −  j Dψ · n  2 A 2
              ∂t                                                i · F w , F wy = j · F w , and F wz = k · F w as follows:
                                                ˙
                    −  j  · n  1 A 1 −  j  · n  w A w + R ψ V,  (46)
                       Dψ           Dψ
                                                                     F wx =−p 1 A 1 cos φ 1 + p 2 A 2 cos φ 2
                                                       ˙
              where   is the total content of ψ in volume V and R ψ is     − ρ v  A 1 cos φ 1 + ρ vx A 2 cos φ 2   (52)
                                                                                2
                                                                                               2
                                                                                               2
                                                                                1
              the volume average rate of production of ψ in V . In this
              relation the caret brackets have the significance       F wy =−p 1 A 1 sin φ 1 + p 2 A 2 sin φ 2
                                                                                2              2
                                  1                                        − ρ v  A 1 sin φ 1 + ρ v  A 2 sin φ 2  (53)

                                                                                               2
                                                                                1
                         () · n  k ≡   [( ) · n] k ds,  (47)
                                  A k                                F wz = ρVg                           (54)
                                     A k
              which is simply a statement of the mean value theorem of
              calculus applied to the integral in question. Equation (46)
              is an averaged or macroscopic form of the general bal-
              ance relation and can be applied to mass, momentum, and
              energy.
              A. Equation of Continuity
              As before, there are no generation or diffusion terms for
              mass, so Eq. (46) becomes
                         ∂m
                             = ρ( v  1 A 1 − v  2 A 2 ).  (48)
                          ∂t
              The vast majority of practical chemical engineering prob-
              lems are in steady-state operation, so that Eq. (48) reduces  FIGURE 2 Illustration of forces on a pipe bend.
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