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 Encyclopedia of Physical Science and Technology  EN009N-447  July 19, 2001  23:3







              Microwave Molecular Spectroscopy                                                            823

              TABLE XIII Geometries for Selected Complexes
                     Complex                 Geometry                              Reference
                                   Triangular                   Bumgarner, R. E., and Kukolich, S. G. (1987). J. Chem. Phys. 86, 1083


                                   Planar, T-shaped, C 2V       Legon, A. C., Aldrich, P. D., and Flygare, W. H. (1981). J. Chem. Phys.
                                                                 75, 625

                                   Cis, planar                  Kukolich, S. G. (1983). J. Mol. Spectrosc. 98, 80


                                   Nonplanar, cyclic            Bumgarner, R. E., Pauley, D. J., and Kukolich, S. G. (1987). J. Chem.
                                                                 Phys. 87, 3749

                                   Planar, T-shaped, C 2V       Gutowsky, H. S., Klots, T. D., Chuang, C., Schmuttenmaer, C. A., and
                                                                 Emilsson, T. (1987). J. Chem. Phys. 86, 569


                                   C 3V symmetric top, H F along C 3  Gutowsky, H. S., Klots, T. D., Chuang, C., Keen, J. D., Schmuttenmaer,
                                     axis of Ar 3 group, H closest to Ar 3  C. A., and Emilsson, T. (1987). J. Am. Chem. Soc. 109, 5633
                                   Symmetric top, HCN along C 3 axis of  Gutowsky, H. S., Hajduk, P. J., Chuang, C., and Ruoff, R. S. (1990).
                                     cyclic (CO 2 ) 3 group, N closest to  J. Chem. Phys. 92, 862
                                     (CO 2 ) 3
                                   Linear HCN trimer            Ruoff, R. S., Emilsson, T., Klots, T. D., Chuang, C., and Gutowsky,
                                                                 H. S. (1988). J. Chem. Phys. 89, 138
                                   T-shaped, C 2v symmetry      Lida, M., Ohshima, Y., and Endo, Y. (1991). J. Chem. Phys. 94, 6989




                                   Ar above thiazole ring shifted toward  Kretschmer, U., Stahl, W., and Dreizler, H. (1995). J. Mol. Struct.
                                     N atom                      352, 289







                                   T-shaped, C 2v symmetry      Mader, H., Heineking, N., Stahl, W., Jager, W., and Xu, Y. (1996).
                                                                 J. Chem. Soc. Faraday Trans. 92, 901



                                   S···Cl Cl collinear, Cl 2 nearly  Bloemink, H. I., Dolling, S. J., Hinds, K., and Legon, A. C. (1995).
                                     perpendicular to H 2 S plane  J. Chem. Soc. Faraday Trans. 91, 2059
                                   Water-donor, methanol-acceptor complex  Stockman, P. A., Blake, G. A., Lovas, F. J., and Suenram, R. D. (1997).
                                                                 J. Chem. Phys. 107, 3782



                                   Induced dipole ∼0.01 D       Jager, W., Xu, Y., and Gerry, M. C. L. (1993). J. Chem. Phys. 99, 919
                                   Heavy atoms, approximately collinear,  Yaron, D., Peterson, K. I., Zolandz, D., Klemperer, W., Lovas, F. J., and
                                     H 2 O···O hydrogen bond     Suenram, R. D. (1990). J. Chem. Phys. 92, 7095
                                   Xe, Kr complexes T-shaped, Ne complex  Walker, K. A., Ogata, T., Jager, W., Gerry, M. C. L., and Ozier, I.
                                     tilted as shown             (1997). J. Chem. Phys. 106, 7519


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