Page 340 - Academic Press Encyclopedia of Physical Science and Technology 3rd Analytical Chemistry

P1: GNH/FEE P2: GPJ Final Pages
Encyclopedia of Physical Science and Technology EN010C-493 July 19, 2001 20:30

Nuclear Magnetic Resonance (NMR) 705

TABLE I (Continued )
Resonance
Atomic Natural Quadrupole Gyromagnetic frequency
1
7
weight/ abundance Sensitivity moment ratio (10 rad ( H TMS
2
element Spin (%) (versus 13 C) (10 −28 M ) T −1 sec −1 ) 100 MHz)
81 3 2
Br 49.46 2.77 × 10 0.28 7.2246 27.007
2
83 Kr 9 2 11.55 1.23 0.15 −1.029 3.848
85 Rb 5 72.15 43 0.25 2.5828 9.655
2
87 Rb 3 27.85 2.77 × 10 2 0.12 8.7532 32.721
2
87 9
Sr 7.02 1.07 0.36 −1.1593 4.334
2
89 Y 1 100 0.668 — −1.3108 4.900
2
91 Zr 5 11.23 6.04 −0.21 −2.4868 9.296
2
93 Nb 9 100 2.740 × 10 3 −0.2 6.5476 24.476
2
95 5
Mo 15.72 2.88 ±0.12 1.7433 6.517
2
97 5
Mo 9.46 1.84 ±1.1 −1.7799 6.654
2
99 Tc 9 2 100 1.562 × 10 3d −0.19 d 6.0211 22.508
99 Ru 5 12.72 0.83 7.6 × 10 −2 −1.2343 4.614
2
101 Ru 5 17.07 1.56 0.44 −1.3834 5.171
2
103 1
Rh 100 0.177 — −0.8520 3.185
2
105 Pd 3 22.23 1.41 0.8 −0.756 4.576
2
107 Ag 1 2 51.82 0.195 — −1.0828 4.048
109 Ag 1 48.18 0.276 — −1.2448 4.654
2
111 1
Cd 12.75 6.73 — −5.6714 21.201
2
113 1
Cd 12.26 7.6 — −5.9328 22.178
2
113 In 9 2 4.28 83.8 1.14 5.8493 21.866
115 In 9 95.72 1.89 × 10 3 0.83 5.8618 21.913
2
115 Sn 1 0.35 0.695 — −8.792 32.86
2
117 1
Sn 7.61 19.54 — −9.5319 35.632
2
119 Sn 1 8.58 25.2 — −9.9756 37.291
2
121 Sb 5 2 57.25 5.20 × 10 2 −0.53 6.4016 23.931
123 Sb 7 42.75 1.11 × 10 2 −0.68 3.4668 12.959
2
123 1
Te 0.89 0.89 — −7.0006 26.170
2
125 1
Te 7.0 12.5 — −8.4398 31.550
2
127 I 5 2 100 5.3 × 10 2 −0.79 5.3525 20.009
129 Xe 1 26.44 31.8 — −7.4003 27.658
2
131 Xe 3 21.18 3.31 −0.12 2.1939 8.200
2
133 7 2 −3
Cs 100 2.69 × 10 −3 × 10 3.5087 13.116
2
135 Ba 3 6.59 1.83 0.18 2.6575 9.934
2
137 Ba 3 2 11.32 4.41 0.28 2.9728 11.113
138 La 5 0.09 0.43 −0.47 3.5295 13.194
139 La 7 99.91 3.36 × 10 2 0.21 3.7787 14.126
2
141 Pr 5 100 1.66 × 10 3 −5.9 × 10 −2 7.836 29.291
2
143 7
Nd 12.17 2.31 −0.48 1.455 5.438
2
145 Nd 7 8.3 0.37 −0.25 0.895 3.346
2
147 Sm 7 14.97 1.26 −0.21 1.104 4.128
2
149 Sm 7 13.83 0.59 6 × 10 −2 0.880 3.289
2
151 5 2
Eu 47.82 4.83 × 10 1.16 6.634 24.801
2
153 5
Eu 52.18 45.3 2.9 2.930 10.952
2
155 Gd 3 2 14.73 0.23 1.6 1.022 3.820
157 Gd 3 15.68 0.48 2 1.277 4.775
2
159 Tb 3 100 3.31 × 10 2 1.3 6.067 22.679
2
(continues)