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64    Energy from Toxic Organic Waste for Heat and Power Generation



                                             Organic polymers
                                        Fats, proteins, poly-saccharides

                  Hydrolysis              Fermentative   NH , S 2–
                                                            +
                                       micro-organisms      4
                                     4%             76%         20%
                                                Alcohols,
                                               +
                                             C carboxylic acids
                                              3
                Acetogenesis
                                          24%             52%
                                                Acetogens
                                        H , CO 2          Acetate
                                         2
                                             Homoacetogenesis
                               Hydrogenophilic           72%  Acetophilic
              Methanogenesis     methanogens  28%            methanogens
                                                CH 4 , CO 2
          Fig. 5.2  Process flow of biomethanation.


          reactor types (fully mixed, plug-flow, biofilm, UASB, etc.) and process con-
          ditions (retention times, loading rates, temperatures, etc.) in order to maxi-
          mize the energy output from the waste and also to decrease retention time
          and  enhance process stability. Biomethanation has strong potential for the
          production of energy from organic residues and wastes. It will help to re-
          duce the use of fossil fuels and thus reduce CO 2  emission [53]. The process
          flow of biomethanation [54] is depicted in Fig. 5.2.
             In this section, the economic importance of leather industry, the stages
          involved in leather processing, and the chemicals involved are presented.
          Later, the waste produced from leather processing along with the classi-
          fication of the toxic substances is explained. Finally, the two appropriate
          methods through which the toxic waste from the leather industry may be
          utilized to generate heat and energy generation are stated.


          REFERENCES

            [1]  Dixit S, Yadav A, Dwivedi PD, Das M. Toxic hazards of leather industry and  technologies
              to combat threat: a review. J Clean Prod 2015;87:39–49.
            [2]  International Trade Centre, http://www.intracen.org/itc/sectors/leather/.
            [3]  Kolomazník  K,  Adámek  M,  Andel  I, Uhlirova  M. Leather waste—potential
              threat to human health, and a new technology of its treatment. J Hazard Mater
              2008;160(2):514–20.
            [4]  Hüffer S, Taeger T. Sustainable leather manufacturing: a topic with growing  importance.
              J Am Leather Chem Assoc 2004;99(10):424–8.
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