Page 85 - Energy from Toxic Organic Waste for Heat and Power Generation
P. 85

Toxic Waste From Biodiesel Production Industries and Its Utilization   71


              3.  Higher cost
              4.  Reactivity of unsaturated hydrocarbon chains
              5.  Affects food chain
                 Properties of various edible plant oils are listed in Table 6.1. Plant oil
              viscosity has been reduced drastically when it is blended with petroleum
              diesel with proper ration (5%–20%) and the engine can handle the blended
              fuel without any engine modification. The conversion of edible plant oils
              into fatty acid methyl esters (FAME) is an effective way to overcome all the
              problems associated with the plant oils [2].
                 Biodiesel production from edible plant oils purely depends on availabil-
              ity of resources and cost of raw materials. On the other hand, extensive use
              of edible plant oils may cause other important problems such as starvation,
              which means a rise of biomass price, increase in water requirement, and
              problem with availability of water. Therefore, biodiesel produced from edi-
              ble plant oils is presently not economically feasible [6].

              6.2.1.2  Plant Oils (Nonedible)
              In order to rectify the problems from edible plant oils, researches have been
              made to derive biodiesel by using nonedible plant oils. Nonedible plant oils
              are economically suitable for biodiesel production compared to food-grade
              plant oils [7]. The advantages of nonedible plant oils as a diesel fuel are their
              liquid nature portability, higher combustion efficiency, ready availability, re-
              liability, aromatic content, and lower sulfur and higher biodegradability [6].
              Properties of some nonedible plant oils are listed in Table 6.2. The cetane
              number is an essential parameter for identification of ignition quality of




              Table 6.1  Properties of selected plant oils (edible type) [2]
                                                                     Viscosity
                                                                         2
                         Lodine   Cetane   Cloud   Pour     Flash    (mm /s)
              Oil        value    number  point (K)  point (K)  point (K)  @ 313 K
              A. indica  82–98    –       286.0    280.0    –        35.83
              J. curcas  101      23      283.0    267.0    459      35.4
              M. indica  65       –       287.0    288.0    499      25.0
              P. pinnata  87      42      276.5    279.0    498      40.2
              R. communis  84.4   42.0    274.0    259.0    >533     240.1
              Rapeseed   94–120   37.6    269.1    241.3    519      37.0
              Soybean    117–143 37.9     269.1    260.8    527      32.6
              Sunflower  110–143 37.1     280.2    258.0    547      37.1
   80   81   82   83   84   85   86   87   88   89   90