Page 311 - Engineered Interfaces in Fiber Reinforced Composites
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292                Engineered interfaces in fiber reinforced composites

                                     1.6
                                  a
                                  5 1.4-
                                  CJ)                   0
                                  2  1.2-
                                               0.. 0.
                                  g m  1:                       0   a
                                     0.8  -                              0
                                  x      -
                                  '-  0.6
                                  .E  - 0.4  -
                                   a
                                   E  0.2-
                                                            I   .   I
                                                                            ,4




                                      1.41

                                  .- 5 0.4 t


                                     0.8
                                   N
                                  3 0.6
                                   E
                                  z



                                       "    0      0.1     0.2     0.3     0.4
                                  (b)            Coating thickness, P m

                     Fig. 7.8. (a) Normalized impact fracture toughness and (b) interlaminar shear strength (ILSS) of carbon
                     fiber-epoxy matrix composites as a function of  glycidyl  acrylate/methyl acrylate (GA/MA) interlayer
                                           thickness. After Rhee and Bell  (1991).

                        the  longitudinal  and  transverse  directions,  in  particular  for  those  coatings
                        providing a low bond strength with the fibers. Systematic reductions in flexural
                        strength and ILSS with increasing coating thickness, e.g. silicon rubber coating
                        (Hancox and Wells, 1977) and polyvinyl acetate (PVA) coating (Kim and Mai,
                         1991b), have been reported.
                     (4)  There are contradicting views with regard to the reactivity and miscibility of the
                        coating material with the resin matrix during curing. Sung et al. (1977) suggested
                        that  the coating should form and  remain in  a  discrete layer  at  the  interface
                        without reaction with the composite constituents. However, a certain degree of
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