Page 307 - Engineered Interfaces in Fiber Reinforced Composites
P. 307

288               Engineered interfaces in fiber reinforced Composites

                                   A  200
                                                                   Prediction
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                                   (b)            TEMPERATURE (T)
                    Fig. 7.5. (a) Transverse impact fracture toughness and (b) fiber pull-out length versus testing temperature
                    for carbon fiber-epoxy matrix composites with and without PVAL coatings on fibers. After Kim and
                                                  Mai et al. (1991b).
                    chemical bonding between the functional groups present  in the fiber surface and
                    epoxy matrix.
                      Several different thermoplastic materials including, polyamide (PA),  polyether
                     sulfone (PES),  polycarbonate  (PC),  polysulfone  (PS),  polyetherimide (PEI)  and
                    polymethyl methacrylate (PMMA), were also found to have significant effects on the
                    mechanical properties  of  carbon  fiber-nylon  matrix  composites (Tomlinson and
                     Barnes, 1992). Polyamide nylon 6.6 coating on carbon and Kevlar fibers for epoxy
                     matrix  composites by  in-situ  polymerization  techniques  were  also  shown  to  be
                     effective for  promoting  localized plastic  deformation  around  the  crack  tip  and
                     protecting the brittle fiber surface during processing (Skourlis et  al.,  1993; Duvis
                     et  al.,  1993).  The  thermoplastic  coatings  have  advantages  over  other  coating
                     materials in that they would form a microductile layer at the interface (Dauksys,
                     1973). The interlayer functions satisfactorily as a stress relief medium in reducing the
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