Page 323 - Engineered Interfaces in Fiber Reinforced Composites
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304               Engineered interfaces m fiber reinforced composites

                                    1.21                                    I















                                   -0.4
                                       0       0.1      0.2       0.3      0.4
                                (a)             Coating thickness, t/a

                                    1.2-

                                 v)
                                 u)
                                 E 0.8-
                                 +                    --.
                                 v)
                                 7 0.6-
                                 5                                    ---___
                                  2  0.4-
                                 -                                        ---.
                                  $  0.2-
                                 -a                          -.
                                 2    0-                                -.
                                       -
                                                                           -.
                                    -0.2             Increase in  ai   -*.   --.
                                    -0.4 -
                                        0       0.1      0.2      0.3      0.4
                                 (b)            Coating thickness, t/a
                    Fig.  7.14.  Normalized  radial  residual  stresses  as  a  function  of  coating  thickness,  ?/a, for  varying
                    coefficients of thermal expansion (CTE) of the coating, a, = 10,70,130 x  10-6/oC: (a) Young’s modulus
                                ratio Ei/Em = 0.333; (h) Ei/Em = 1.0. After Kim and Mai (1996a, b).

                    summary, if the residual stresses at the interfaces are to be reduced substantially, the
                    interlayer material should have a high (~i value, unless its Young’s modulus is much
                    lower than that of the matrix (i.e. Ei/E,,, less than approximately 0.1 for the CFRP
                    studied). This conclusion is considered to be consistent with the criteria proposed for
                    Sic fiber-Ti3Al + Nb matrix composites (Arnold and Wilt, 1992).
                      In the light of the work presented in the foregoing from both the theoretical and
                    experimental viewpoints,  three  concepts of  engineered interfaces  have  been  put
                    forward  to  explain  the  roles  of  the  thermoplastic  coating,  and  their  physical/
                    chemical requirements for three different functional coatings are proposed by Kim
                    and Mai (1996b):
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