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CHAPTER 5  Conductors and Dielectrics         127

                         Intrinsic semiconductors also satisfy the point form of Ohm’s law; that is, the
                     conductivity is reasonably constant with current density and with the direction of the
                     current density.
                         Thenumberofchargecarriersandtheconductivitymaybothbeincreaseddramat-
                     ically by adding very small amounts of impurities. Donor materials provide additional
                     electrons and form n-type semiconductors, whereas acceptors furnish extra holes and
                     form p-type materials. The process is known as doping, and a donor concentration in
                                                                                       5
                                             7
                     silicon as low as one part in 10 causes an increase in conductivity by a factor of 10 .
                         The range of value of the conductivity is extreme as we go from the best insulating
                     materials to semiconductors and the finest conductors. In siemens per meter, σ ranges
                     from 10 −17  for fused quartz, 10 −7  for poor plastic insulators, and roughly unity for
                                            8
                     semiconductors to almost 10 for metallic conductors at room temperature. These
                     values cover the remarkably large range of some 25 orders of magnitude.

                        D5.7. Using the values given in this section for the electron and hole mo-
                        bilities in silicon at 300 K, and assuming hole and electron charge densities
                                     3
                                                     3
                        are 0.0029 C/m and −0.0029 C/m , respectively, find: (a) the component of
                        the conductivity due to holes; (b) the component of the conductivity due to
                        electrons; (c) the conductivity.
                        Ans. 72.5 µS/m; 348 µS/m; 421 µS/m



                     5.7 THE NATURE OF DIELECTRIC
                            MATERIALS

                     A dielectric in an electric field can be viewed as a free-space arrangement of mi-
                     croscopic electric dipoles, each of which is composed of a positive and a negative
                     charge whose centers do not quite coincide.These are not free charges, and they cannot
                     contribute to the conduction process. Rather, they are bound in place by atomic and
                     molecular forces and can only shift positions slightly in response to external fields.
                     They are called bound charges, in contrast to the free charges that determine conduc-
                     tivity. The bound charges can be treated as any other sources of the electrostatic field.
                     Therefore, we would not need to introduce the dielectric constant as a new parameter
                     or to deal with permittivities different from the permittivity of free space; however,
                     the alternative would be to consider every charge within a piece of dielectric material.
                     This is too great a price to pay for using all our previous equations in an unmodified
                     form, and we shall therefore spend some time theorizing about dielectrics in a quali-
                     tative way; introducing polarization P, permittivity  , and relative permittivity   r ; and
                     developing some quantitative relationships involving these new parameters.
                         The characteristic that all dielectric materials have in common, whether they are
                     solid, liquid, or gas, and whether or not they are crystalline in nature, is their ability
                     to store electric energy. This storage takes place by means of a shift in the relative
                     positions of the internal, bound positive and negative charges against the normal
                     molecular and atomic forces.
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