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CHAPTER EIGHT




              Fluid-rock interactions




              Abstract
                 This chapter discusses the research results on the interactions between an aqueous so-
                 lution and a clay-bearing rock. The effects of confining stress, bedding, existing natural
                 fractures, low-pH and carbonated water, high-pH water and surfactants on the perme-
                 ability changes from water-rock interactions are discussed. The effects of some of those
                 factors on rock mechanical properties are also discussed. Some reactions which induce
                 fractures are introduced.

              Keywords: Confining stress; Fluid-rock interactions; Mechanical properties; Natural
              fractures; Permeability changes; pH; Reaction-induced fractures; Surfactants.


                   8.1 Introduction

                   The fluid-rock interactions to be discussed in this chapter are the
              interactions between an aqueous solution and a clay-bearing rock. There
              are three reasons we need to study the interactions in shale and tight reser-
              voirs: (1) most of fracturing fluids are aqueous fluids; (2) most of chemicals
              are injected through aqueous fluids; (3) water injection may still be a practical
              EOR method. In conventional reservoirs, it is generally accepted that water-
              rock swelling may cause formation damagedreducing formation perme-
              ability. However, there are some discrepancies in shale reservoirs regarding
              the results of water-rock interactions. Some believe water-rock interactions
              also cause formation damage. Some argue that water-rock interactions, espe-
              cially the interactions between water and shale, may generate microfractures
              or reopen existing natural fractures; therefore, formation may not be
              damaged, instead, it may be stimulated. This chapter is to discuss the research
              results on the interactions between water and a clay-bearing rock.


                   8.2 Evidences of microfractures generated or existing
                   natural fractures reopened

                   Many papers have been published on water-rock interaction. It is
              commonly accepted that water-rock interaction causes formation damage


              Enhanced Oil Recovery in Shale and Tight Reservoirs  © 2020 James Sheng.
              ISBN: 978-0-12-815905-7                  Published by Elsevier Inc.
              https://doi.org/10.1016/B978-0-12-815905-7.00008-6  All rights reserved.  173 j
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