Page 217 - Enhanced Oil Recovery in Shale and Tight Reservoirs
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200                            Enhanced Oil Recovery in Shale and Tight Reservoirs


          Table 8.2 Pump schedule in a Woodford shale frac. job (Grieser et al., 2007).dcont'd
                                                 Conc., Ibm/
          Stage       Vol., gal   Fluid          gal       Proppant
          22 Sand slug 14,240     Treated water  0.64      Premium
                                                             Brown-30/70
          23 Sand slug 14,240     Treated water  0.73      Premium
                                                             Brown-30/70
          24 Sand slug 14,240     Treated water  0.82      Premium
                                                             Brown-30/70
          25 Sand slug 14,240     Treated water  0.9       Premium
                                                             Brown-30/70
          26 Flush    3,655       Pad and flush


          shale frac job. About 3% HCl was used in the acid pad. The total acid pad
          volume was about one-third of the total fracturing fluid volume.
             Carbon dioxide (CO 2 ) EOR is a popular EOR method. CO 2 injection
          results in carbonate water because there is generally water in reservoirs.
          Carbonated water is a low-pH solution. Takahashi and Kovscek’s (2009)
          experiments showed that the oil recovery factors of spontaneous countercur-
          rent imbibition from carbonated water and HCl (low-pH) are similar
          (Fig. 8.23). The oil recovery factors from neutral pH brine and a high-pH



                   0.5
                                                      Brine
                  0.45                                Carbonated water, No.1
                                                      Carbonated water, No.2
                   0.4                                HCI brine (pH3), No.1
                                                      HCI brine (pH3), No.2
                  0.35                                NaOH brine (pH12)
                 OlP recovered  0.25
                   0.3


                   0.2
                  0.15
                   0.1
                  0.05
                    0
                     10 1           10 2           10 3           10 4
                                         Time, min
          Figure 8.23 Oil recovery of spontaneous countercurrent imbibition of different pH
          brines (Takahashi and Kovscek, 2009).
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