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224                            Enhanced Oil Recovery in Shale and Tight Reservoirs


          theeffectsofwettabilityandIFTreductiononend-pointrelativepermeabilities
          and exponents are based on their effects on residual saturations.
             First, a simple interpolation technique is used to consider the wettability
          effect only (no IFT or capillary number effect) on a residual saturation:
                                     WA
                             S WA    S r;b1  S WA    S WA
                               rj
                                                    r;b1
                                             r;b2
                                         ¼                           (9.24)
                             cos q   cosq b1  cosq b2   cosq b1
             In the above equation, the superscript “WA” refers to the parameter
          value when only wettability alteration is considered. The subscripts b1 and
          b2 represent two wetting cases that correspond to the two wetting angles
          q b1 and q b2 . Then the effect of IFT or capillary number (trapping number)
          on the residual saturation is considered using Eq. (9.14).
             The above two procedures generate one conventional (without effect of
          wettability) capillary desaturation curve (CDC) for one wetting angle, and the
          effect of wettability will be reflected by a series of CDC curves with each
          CDC corresponding to one wetting angle. Practically, two CDC curves for
          each phase are defined; one corresponds to the strongly water-wetting case,
          and the other the strongly oil-wetting case.
             Once the residual saturations are defined in terms of the effects of wetta-
          bility alteration and IFT, the end-point relative permeabilities are estimated
          directly from the residual saturations, following Eq. (9.15);and the exponents
          are estimated similarly.

          9.4.4 CMG-STARS model
          The above mathematical models may not readily be available to a practical
          engineer or it may not be convenient for the engineer to code the models.
          Instead, a commercial simulator is more convenient. In this section, a
          CMG-STARS model is presented.
             In the CMG-STARS (Computer Modeling Group, 2016) model, it is
          assumed that the degree of wettability alteration is scaled by the amount
          of surfactant adsorbed. The surfactant adsorption isotherm is described by
          the Langmuir-type isotherm:

                                           ax sw
                                    G s ¼                            (9.25)
                                         1 þ bx sw
          where G s is the adsorbed surfactant, a and b are adsorbing constants for
          Langmuir-type isotherm obtained by matching adsorption experiments, and
          x sw is the surfactant mole fraction in the aqueous surfactant solution. The
          above equation assumes that the adsorbed surfactant is much less than the
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