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454                            Enhanced Oil Recovery in Shale and Tight Reservoirs


          air requirement is related to minimum fuel required to maintain the
          combustion. Barzin et al. (2010) reported that the air requirement for typi-
                                               3
                                     3
          cally high gravity oil is 173 m (STC)/m ; Martin et al. (1958) reported
               3         3
          135 m (STC)/m . But several times of these numbers were reported in field
          projects.

               13.9 EOR mechanisms and EOR potential in shale and
               tight reservoirs

               Fassihi and Kovscek (2017) listed these mechanisms of air injection in
          light oil reservoirs:
          (1) stripping and vaporizing light oil components by generated CO 2 ;
          (2) sweeping oil by combustion gases and possible miscibility effects;
          (3) oil banking and improved sweep;
          (4) pressurization and voidage replacement;
          (5) reducing oil viscosity due to increased temperature.
             These mechanisms are all related to combustion. However, whether
          combustion, especially by spontaneous ignition, in light oil reservoirs can
          occur or sustain is still a question. In high-temperature combustion, pressure
          is maintained. But in LTO, pressure is reduced as oxygen consumed is
          greater than carbon dioxide release (Turta and Singhal, 2001). In Zhang
          and Sheng’s (2016) small batch reactor experiments, both the oxygen partial
          pressure and the total pressure decreased with time (see Fig. 13.28). There-
          fore, the pressurization (the above mechanism 4) from air injection during
          LTO is not more effective from nitrogen or flue gas injection.





















          Figure 13.28 Total system pressure and oxygen pressure in an isothermal (124 C) SBR

          experiment.
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