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102   Environmental Control in Petroleum Engineering


                             Table 3-9
               Role of Trace Metals in Plants and Animals
                                                         Typical
             Essential  Beneficial  Toxic    Toxic    Concentration
 Metal       to Plants to Animals to Plants to Animals   (mg/kg)
 Antimony       No        No         9        Yes         1.5
 Arsenic        No        Yes      Yes        Yes          7
 Barium         No      Possible   Low       Low          500
 Beryllium      No        No       Yes        Yes          2
 Bismuth        No        No       Yes        Yes         0.2
 Boron          Yes       No        Yes       _            20
 Cadmium        No        No       Yes        Yes         0.35
                                                 6+
 Chromium       No        Yes      Yes     Yes (Cr )       75
 Cobalt         Yes       Yes      Low       Low           9
 Copper         Yes       Yes      Yes        Yes          22
 Lead           No        No       Yes        Yes          25
 Manganese      Yes      Yes       Yes       Low          700
 Mercury        No        No        No        Yes         0.07
 Molybdenum     Yes       Yes      Yes        Yes          1.5
 Nickel       Possible    Yes       Yes       Yes          30
 Selenium      Yes       Yes        Yes       Yes         0.3
 Silver         No        No        No        Yes         0.05
 Tin            No       Yes         '?       Yes          4
 Tungsten       No        No         9         ?          1.5
 Vanadium      Yes       Yes       Yes        Yes         75
 Zinc           Yes      Yes       Yes        Yes         60

 Source: adapted from Logan and Traina, 1993.
 Reprinted from Metals in Groundwater, with permission. Copyright Lewis Publishers, an
 imprint of CRC Press, Boca Raton, Florida.


 (1989), Calabrese and Kenyon (1991), St. Pe et al. (1990), and the
 American Petroleum Institute (1981b).
 Antimony: Inhalation can cause dermatitis, keratitis, conjunctivitis, and
 nasal septum ulceration. Amounts greater than about 0.1 g are considered
 to be lethal to humans by ingestion. Antimony shortens lifespan when fed
 to rats and mice. It also causes phenmonitis and heart and liver damage.

 Arsenic: Chronic exposure to arsenic can lead to weakness, anorexia,
 bronchitis, gastrointestinal disturbances, peripheral neuropathy, skin
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