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34   Environmental Control in Petroleum Engineering


 (American Petroleum Institute, 1990b). The larger flocculates then
 settle more rapidly in the mud pits. This process involves the neu-
 tralization of the surface charge (zeta potential) on suspended par-
 ticles to overcome coulombic electrical repulsion between the par-
 ticles and allow aggregates to form. Inducing alternating electrical
 currents to overcome the coulombic repulsion has also been proposed
 (Farrell, 1991).
   If a drilling mud contains gas that is not removed by the solids
 separation equipment, a vacuum chamber can be added to the mud
 system. This lowers the mud pressure in the chamber and expands the
 size of the gas bubbles, allowing them to be separated from the liquid
 by gravity more rapidly. In these systems, the mud is typically passed
 over inclined planes in thin layers to enhance separation.
   If the proper equipment and procedures are not used to remove the
 cuttings as they are added to the mud system, the concentration of
 cuttings in the mud gradually increases with time, and the mud
 properties, such as density and viscosity, are degraded. The maxi-
 mum tolerable solids concentration varies with the mud used, but is
 generally between 4% and 15% (Wojtanowicz, 1991). To maintain the
 mud properties in the desirable range, the mud can be diluted; this
 requires the addition of more base fluid, either water or oil, and many
 of the chemicals needed to alter its chemical properties. Dilution,
 however, increases the volume of drilling waste that must ultimately
 be disposed of.
   In many cases, shale shakers and settling pits are insufficient to
 separate the mud solids from liquids, and further treatment with
 advanced technology is required. For example, after separating the
 solids from the mud, a significant volume of liquid is normally
 retained with the cuttings. Volumetric measurements from offshore
 platforms have shown that the total volume of liquids with the cuttings
 after discharge can be from 53% to 73% (Wojtanowicz, 1991). In some
 cases, further dewatering of the solids may be required before disposal.
 Advanced separation methods are discussed in Chapter 6.
   One difficulty with using advanced technology for improved separa-
 tions at a drill site is the high cost of equipment rental. The expendi-
 ture for this equipment can be easier to justify if a good economic
 model for their benefits is used. One such model has been proposed
 by Lai (1988) and was subsequently verified by field performance (Lai
 and Thurber, 1989).
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