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Basic Thermodynamics, Fluid Mechanics: Definitions of Efficiency  29
                          widely used name rothalpy, a contraction of rotational stagnation enthalpy, and is
                          a fluid mechanical property of some importance in the study of relative flows in
                                                                        Ł
                          rotating systems. As the value of rothalpy is apparently unchanged between entry
                          and exit of the impeller it is deduced that it must be constant along the flow lines
                          between these two stations. Thus, the rothalpy can be written generally as
                                     1 2
                              I D h C c   Uc   .                                         (2.12e)
                                     2
                            The same reasoning can be applied to the thermomechanical flow through a
                          turbine with the same result.


                          The second law of thermodynamics            entropy

                            The second law of thermodynamics, developed rigorously in many modern ther-
                          modynamic textbooks, e.g. ¸Cengel and Boles (1994), Reynolds and Perkins (1977),
                          Rogers and Mayhew (1992), enables the concept of entropy to be introduced and
                          ideal thermodynamic processes to be defined.
                            An important and useful corollary of the second law of thermodynamics, known as
                          the Inequality of Clausius, states that for a system passing through a cycle involving
                          heat exchanges,
                              I
                                 dQ
                                    5 0,                                                  (2.13)
                                 T
                          where dQ is an element of heat transferred to the system at an absolute temperature
                          T. If all the processes in the cycle are reversible then dQ D dQ R and the equality
                          in eqn. (2.13) holds true, i.e.
                              I
                                 dQ R
                                     D 0.                                                (2.13a)
                                  T
                          The property called entropy, for a finite change of state, is then defined as
                                         2
                                       Z
                                          dQ R
                                  S 1 D       .                                           (2.14)
                              S 2
                                        1  T
                          For an incremental change of state
                                         dQ R
                              dS D mds D     ,                                           (2.14a)
                                          T
                          where m is the mass of the system.
                            With steady one-dimensional flow through a control volume in which the fluid
                          experiences a change of state from condition 1 at entry to 2 at exit,

                              Z
                                2  P
                                 dQ
                                     5 Pm.s 2  s 1 /.                                     (2.15)
                                  T
                               1
                            Ł  A discussion of recent investigations into the conditions required for the conservation of rothalpy
                          is deferred until Chapter 7.
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