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Hydraulic Oils and Theor etical Backgr ound    47


                    •  Water/polymer—water glycol (35% water minimum, 80%
                      maximum)
                    •  Pure chemical fluids; water-free
                    •  Phosphate esters
                    •  Chlorinated hydrocarbons
                    •  Mixture of phosphate esters and chlorinated hydrocarbons

               2.3.2 Mineral Oils
               Mineral-based oils are the most widely used hydraulic fluids. They
               are relatively inexpensive, widely available, and can be offered in
               suitable viscosity grades. They are of good lubricity, noncorrosive,
               and are compatible with most sealing materials with the exception of
               butyl rubber.
                   Mineral oils are chemically stable for reasonable operating tem-
               peratures.  At higher temperatures, however, they suffer chemical
               breakdown. Premium grade mineral oils contain a package of addi-
               tives to combat the effects of wear, oxidation, and foam formation,
               and to improve viscosity index and lubricity. There are, however,
               certain disadvantages of mineral oils that cannot be remedied by in-
               corporating additives. The two most important are the flammability
               and the increase in viscosity at high pressures. Fire risk excludes the
               use of mineral oils in hazardous areas such as injection and plastic
               molding machines, coal mines, and near furnaces. The viscosity-
               pressure characteristics limit their use to pressures below 1000 bar
               (see Fig. 2.3).

               2.3.3 Fire-Resistant Fluids

               Oil-in-Water Emulsion
               This hydraulic fluid consists of tiny droplets of oil dispersed in a con-
               tinuous water phase. The dilution is normally between 2% and 5% oil
               in water, and the characteristics of the fluid are more similar to water
               than oil. It is extremely fire-resistant, is highly incompressible, and has
               good cooling properties. Its main disadvantages are poor lubricity
               and low viscosity.


               Water-in-Oil Emulsion
               The water-in-oil emulsions are the most popular fire-resistant flu-
               ids. They have a continuous oil phase in which tiny droplets of
               water are dispersed. Their lubrication properties are very much
                reduced. This is partially overcome by running pumps at reduced
               speeds. Therefore, larger displacement pumps are necessary to
               obtain the required flow rate. The usual dilution is 60% oil + 40%
               water. For optimum life, the operating temperatures should not
                exceed 25°C, but intermittent operation up to 50°C is permissible.
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