Page 72 - Fluid Power Engineering
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Hydraulic Oils and Theor etical Backgr ound    49



          2.4 Additives
               The largest class of hydraulic fluids consists of refined hydrocarbon
               base oils (petroleum oils) and suitable additives to improve the base
               properties. The main types of additives used in hydraulic fluids are
               the following.
                    •  Oxidation inhibitors improve the ability of liquid to withstand
                      chemical reaction with oxygen/air and avoid subsequent
                      degradation. They are of prime importance when operating
                      at elevated temperatures.
                    •  Corrosion inhibitors form molecular layers that are bound to
                      the surface by electrostatic forces and form an effective barrier
                      against penetration by oxygen and water, which is necessary
                      for rust-forming electrochemical reactions.
                    •  Antifoaming agents, which form small heterogeneous areas
                      within the bubble walls of surface foam. Due to their low
                      surface tension, these small areas are weak spots and result in
                      bubble bursting.
                    •  Anti-wear additives of high thermal stability.
                    •  Viscosity index improvers
                    •  Pour point depressants
                    •  Friction modifiers are necessary under certain conditions to
                      ensure smooth operation, free from juddering (stick/slip).
                    •  Detergents are substances providing a cleaning action with
                      respect to the surface deposits.


          2.5  Requirements Imposed on the Hydraulic Liquid
               The following are the main requirements imposed on hydraulic
               liquids:

                    •  Satisfactory flow properties throughout the entire range of
                      operating temperatures.
                    •  A high viscosity index that ensures moderate viscosity
                      variation in relation to the temperature fluctuations.
                    •  Good lubricating properties are a prerequisite to reduce the
                      wear and increase the service life of the system.
                    •  Low vapor pressure to avoid cavitation.
                    •  Compatibility with system materials since the fluid should
                      not react chemically with any of the used materials or
                      deteriorate their physical properties.
                    •  Chemical stability is necessary to increase the service life of
                      liquid and avoid performance deterioration.
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