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1656_FM.fm  Page xiv  Tuesday, May 3, 2005  5:49 PM









                       Part III
                       Material Behavior.........................................................................................................................217


                       Chapter 5
                       Fracture Mechanisms in Metals.....................................................................................................219
                       5.1  Ductile Fracture....................................................................................................................219
                           5.1.1  Void Nucleation........................................................................................................219
                           5.1.2  Void Growth and Coalescence .................................................................................222
                           5.1.3  Ductile Crack Growth ..............................................................................................231
                       5.2  Cleavage................................................................................................................................234
                           5.2.1  Fractography.............................................................................................................234
                           5.2.2  Mechanisms of Cleavage Initiation..........................................................................235
                           5.2.3  Mathematical Models of Cleavage Fracture
                                 Toughness .................................................................................................................238
                       5.3  The Ductile-Brittle Transition..............................................................................................247
                       5.4  Intergranular Fracture...........................................................................................................249
                       Appendix 5:  Statistical Modeling of Cleavage Fracture............................................................250
                                   A5.1 Weakest Link Fracture................................................................................250
                                   A5.2 Incorporating a Conditional Probability
                                        of Propagation ............................................................................................252
                       References ......................................................................................................................................254

                       Chapter 6
                       Fracture Mechanisms in Nonmetals ..............................................................................................257
                       6.1  Engineering Plastics .............................................................................................................257
                           6.1.1  Structure and Properties of Polymers......................................................................258
                                 6.1.1.1 Molecular Weight ......................................................................................258
                                 6.1.1.2 Molecular Structure...................................................................................259
                                 6.1.1.3 Crystalline and Amorphous Polymers ......................................................259
                                 6.1.1.4 Viscoelastic Behavior ................................................................................260
                                 6.1.1.5 Mechanical Analogs ..................................................................................263
                           6.1.2  Yielding and Fracture in Polymers ..........................................................................265
                                 6.1.2.1 Chain Scission and Disentanglement........................................................265
                                 6.1.2.2 Shear Yielding and Crazing.......................................................................265
                                 6.1.2.3 Crack-Tip Behavior ...................................................................................267
                                 6.1.2.4  Rubber Toughening...................................................................................268
                                 6.1.2.5  Fatigue.......................................................................................................270
                           6.1.3  Fiber-Reinforced Plastics .........................................................................................270
                                 6.1.3.1  Overview of Failure Mechanisms.............................................................271
                                 6.1.3.2  Delamination .............................................................................................272
                                 6.1.3.3 Compressive Failure ..................................................................................275
                                 6.1.3.4 Notch Strength...........................................................................................278
                                 6.1.3.5 Fatigue Damage.........................................................................................280
                       6.2  Ceramics and Ceramic Composites .....................................................................................282
                           6.2.1  Microcrack Toughening............................................................................................285
                           6.2.2  Transformation Toughening .....................................................................................286
                           6.2.3  Ductile Phase Toughening........................................................................................287
                           6.2.4  Fiber and Whisker Toughening................................................................................288
                       6.3  Concrete and Rock ...............................................................................................................291
                       References ......................................................................................................................................293
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