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1656_FM.fm  Page xvii  Tuesday, May 3, 2005  5:49 PM









                            10.5.1 Linear Damage Model for Variable Amplitude Fatigue.......................................474
                            10.5.2 Reverse Plasticity at the Crack Tip.......................................................................475
                            10.5.3 The Effect of Overloads and Underloads ............................................................478
                            10.5.4 Models for Retardation and Variable Amplitude Fatigue.....................................484
                       10.6  Growth of Short Cracks......................................................................................................488
                            10.6.1 Microstructurally Short Cracks.............................................................................491
                            10.6.2 Mechanically Short Cracks...................................................................................491
                       10.7  Micromechanisms of Fatigue .............................................................................................491
                            10.7.1 Fatigue in Region II ..............................................................................................491
                            10.7.2 Micromechanisms Near the Threshold.................................................................494
                            10.7.3 Fatigue at High ∆K Values....................................................................................495
                       10.8  Fatigue Crack Growth Experiments ...................................................................................495
                            10.8.1 Crack Growth Rate and Threshold Measurement ................................................496
                            10.8.2 Closure Measurements..........................................................................................498
                            10.8.3 A Proposed Experimental Definition of ∆K ......................................................500
                                                                      eff
                       10.9  Damage Tolerance Methodology........................................................................................501
                       Appendix 10:  Application of The J Contour Integral to Cyclic Loading .................................504
                                    A10.1 Definition of ∆J......................................................................................504
                                    A10.2 Path Independence of ∆J........................................................................506
                                    A10.3 Small-Scale Yielding Limit.....................................................................507
                       References ......................................................................................................................................507

                       Chapter 11
                       Environmentally Assisted Cracking in Metals ..............................................................................511
                       11.1  Corrosion Principles ...........................................................................................................511
                            11.1.1 Electrochemical Reactions....................................................................................511
                            11.1.2 Corrosion Current and Polarization......................................................................514
                            11.1.3 Electrode Potential and Passivity..........................................................................514
                            11.1.4 Cathodic Protection...............................................................................................515
                            11.1.5 Types of Corrosion................................................................................................516
                       11.2  Environmental Cracking Overview ....................................................................................516
                            11.2.1 Terminology and Classification of Cracking Mechanisms ..................................516
                            11.2.2 Occluded Chemistry of Cracks, Pits, and Crevices..............................................517
                            11.2.3 Crack Growth Rate vs. Applied Stress Intensity..................................................518
                            11.2.4 The Threshold for EAC ........................................................................................520
                            11.2.5 Small Crack Effects ..............................................................................................521
                            11.2.6 Static, Cyclic, and Fluctuating Loads...................................................................523
                            11.2.7 Cracking Morphology ...........................................................................................523
                            11.2.8 Life Prediction.......................................................................................................523
                       11.3  Stress Corrosion Cracking..................................................................................................525
                            11.3.1 The Film Rupture Model ......................................................................................527
                            11.3.2 Crack Growth Rate in Stage II .............................................................................528
                            11.3.3 Metallurgical Variables that Influence SCC..........................................................528
                            11.3.4 Corrosion Product Wedging..................................................................................529
                       11.4  Hydrogen Embrittlement ....................................................................................................529
                            11.4.1 Cracking Mechanisms...........................................................................................530
                            11.4.2 Variables that Affect Cracking Behavior..............................................................531
                                   11.4.2.1 Loading Rate and Load History...........................................................531
                                   11.4.2.2 Strength.................................................................................................533
                                   11.4.2.3 Amount of Available Hydrogen ...........................................................535
                                   11.4.2.4 Temperature ..........................................................................................535
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