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356   WETTABILITY OF GAS SHALE RESERVOIRS

                                    20,000                                            40

                                    18,000      10% leak-o                            35
                                                                                 2 2 prop.

                                    16,000      15% leak-o
                                                                                      30
                                    14,000
                                   Imbibed volume (m 3 )  12,000                3     20   Water loss (%)
                                                30% leak-o
                                                                                      25
                                                                                3 prop.
                                    10,000
                                     8,000
                                                                                      15
                                     6,000
                                                                                      10
                                     4,000                                       4 4 prop.
                                     2,000                                            5
                                        0                                             0
                                         0    15   30    45   60    75   90   105   120
                                                           Time (days)

               FIGURE 16.13  Imbibed volume of brine versus the soaking time for the Muskwa shale with different values of fracture aperture.

            fracture aperture size increases the imbibed volume rapidly,   concentration, (ii) is faster along the depositional lamina-
            mainly because fracture–matrix interface increases.  tion, and (iii) decreases with increasing the salt concentration.
                                                                 The data suggest that in addition to capillarity, adsorption
                                                                 effect of clay minerals and osmotic potential influence water
            16.7  INITIAL WATER SATURATION IN                    uptake of gas shales. Furthermore, in contrast to the intact
            GAS SHALES                                           samples, the crushed shale packs imbibe more oil than water.
                                                                 In a crushed sample, both hydrophobic and hydrophilic
            The imbibition experiments reported in this chapter were   pores are well connected. Therefore, the observed difference
            conducted on dry shale samples while in situ shales may   between the oil uptake of crushed and intact samples is
            have some initial water saturation. The initial hydration state   primarily due to the difference in connectivity of pore net-
            can influence the spontaneous imbibition rate in gas/water/  work in crushed and intact samples. In simple, the poorly
            rock systems (Li et al., 2006). However, the initial water sat-  connected hydrophobic pore network of intact samples
            uration of some tight gas (Newsham and Rushing, 2002) and   becomes artificially well connected by crushing the samples.
            gas shale (Wang and Reed, 2009) reservoirs is abnormally   This interpretation is backed by the complete spreading of
            low. Such reservoirs are in a state known as “sub‐irreducible   oil on fresh breaks of all the shale samples studied here.
            initial water saturation,” created by the excessive drying at
            high paleo temperatures and pressures, and the lack of
            sufficient water for increasing the irreducible water satura-  REFERENCES
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                                                                   Unconventional Resources Conference 2014, 1–3 April,  The
                                                                   Woodlands, TX, USA, p 247–262.
            16.8  CONCLUSIONS                                    Agbalaka C, Dandekar AY, Patil SL, Khataniar S, Hemsath JR.
                                                                   The effect of wettability on oil recovery: a review. Paper pre-
                                                                   sented at the SPE Asia Pacific Oil and Gas Conference and
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            the complexity of liquid flow in gas shales. Although the   2008; Perth, Western Australia, Australia, 1, p 73–85.
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            measurements, water uptake of all intact samples is consid-  on well productivity. Paper presented at the Society of Petroleum
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