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30   ORGANIC MATTER‐RICH SHALE DEPOSITIONAL ENVIRONMENTS

            (Broecker, 1969). However, the presence of “widespread”   In continental environments, the composition of shales is
            organic matter‐rich horizons in the deep sea is sometimes   largely dominated by terrigenous material. In terms of
            invoked as evidence for episodes of ocean‐wide stagnation     composition and  texture,  shales  deposited  in  continental
            and/or anoxia, and much modeling effort has been put   environments  are  typically  shales  sensu  stricto,  that  is,
            into creating increasingly complex models that attempt to     laminated and/or fissile organic matter‐rich siliciclastic mud-
            recreate global conditions that explain all occurrences of   stones, and their organic matter is terrigenous. In the marine
            organic matter‐rich sediments in ancient oceans.  While   environment, however, sediments only rarely come from a
            certain stratigraphic intervals are characterized by frequent   single source (Fig. 2.1). Most marine sediments are a mixture
            and/or widespread black shale horizons, the correlation of   of biogenous and terrigenous particles of various grain sizes,
            individual layers is almost always questionable and the   with an additional hydrogenous (authigenic) and/or (very
              petrologic characteristics of the black shales varied. This   minor) cosmogenous component. Biogenous debris, which
            suggests that multiple processes are behind the deposition   may be either calcareous or siliceous, may form a significant
            of not exactly coeval organic matter‐rich sediments during   proportion, if not the majority, of the  inorganic fraction of a
            OAEs (Hay, 1988; Trabucho‐Alexandre et al., 2011); black   shale. The composition of marine shales follows a general
            shales are the product of both local and global conditions   pattern that is related to basin physiography, namely, water
            (cf.  Trabucho‐Alexandre, 2011).  The danger in creating   depth, and ocean circulation (Fig. 2.5).
            “fully detailed models of complex systems is ending up   The relationship between depositional setting and the tex-
            with two things you don’t understand—the system you   ture of shales is more complicated. For example, although
            started with, and your model of it” (Paola and Leeder, 2011).  we  often  think  that  sediment  grain  size  is  a  function  of
                                                                   distance to shore, this is typically not the case, and there are
                                                                 many examples of fine‐grained shores and relatively coarse‐
            2.4.2  Controls on the Geographic Distribution       grained deepwater deposits (e.g., Rine and Ginsburg, 1985;
            of Black Shales
                                                                 Stow, 1985b). In neritic environments below effective wave
            The petrologic characteristics and widespread geographic dis-  base, which are most affected by variations in terrigenous
            tribution of black shales suggest that processes rather than   input and in relative sea level, the variation in seafloor
            environments control their accumulation.  For this reason, a     texture is the most unpredictable, because a significant
                                            6
            discussion concerning their geographic distribution should   fraction of the seafloor is covered in either relict or  palimpsest
            focus on the processes that result in the deposition of organic   sediment (Emery, 1968a; Shepard, 1932).  The texture of
            matter‐rich mud in each environment. In particular, we are   shales is largely independent of environment and therefore
            interested in linking the petrologic characteristics of shales,   more difficult to predict in terms of its geographic  distribution
            that is, their varying composition and texture, with depositional   than composition.
            process and environment. This is important because regional   The sediments of continental margins are different both in
            changes in shale composition and texture due to paleoöceano-  quantity and quality from those on deeper seafloor. Almost
            graphic  and  paleogeographic controls affect,  among other   90% of the total volume of all marine sediment is associated
            things, the economic potential of a rock. Changes in organic   with continental margins, that is, shelves, slopes, and rises,
            matter content and in its nature affect the hydrocarbon genera-  which constitute only about 20% of the ocean’s area. Neritic
            tion potential of a shale, while changes in the relative amounts   sediments, that is, those deposited on the continental shelf,
            of siliciclastic mud and skeletal  biogenous material, calcareous   consist primarily of terrigenous material.  Terrigenous
            and siliceous, affect the mechanical properties of a rock and   material is always ultimately derived from the continent, and
            consequently its behavior when subjected to, for example,   it is brought to the ocean by rivers, coastal erosion, and, to a
            hydraulic stress. The nature of the phases that compose the   lesser extent, wind. The immediate source of the terrigenous
            rock is also  important. Carbonate, for example, may be present   component of a marine sediment, however, is often within the
            as porous biogenous particles or as porosity‐filling diagenetic   marine environment (Meade, 1972). Most terrigenous
            crystals (e.g., dolomite). Likewise, silica may be present as     sediment brought into the ocean by rivers is deposited where
            detrital or authigenic quartz or as porous biogenous silica. The   rivers meet the coastal ocean (e.g.,  Walsh and Nittrouer,
            nature of the phases present in a rock depends on the processes   2009). Sediment that escapes paralic sediment traps and
            and environments behind its formation.                 sediment from coastal erosion tend to travel along the shore
                                                                 within a few kilometers of the coast rather than moving sea-
                                                                 ward (e.g., Manheim et al., 1970; McCave, 1972). Sediment
            6  An environment has been defined as “the complex of physical, chemical,   resuspended from the shelf bottom and sediment transported
            and biological conditions under which a sediment accumulates,” (Krumbein   laterally from offshore constitute the main source of
            and Sloss, 1963, p. 234) and as “a spatial unit in which external physical,   suspended matter on the shelf away from the mouths of large
            chemical, and biological conditions and influences affecting the development
            of a sediment are sufficiently constant to form a characteristic deposit”   rivers. Many ancient black shales were deposited on broad
            (Shepard and Moore, 1955, p. 1488).                  continental shelves at times when sea levels were much
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