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PVT ANALYSIS FOR OIL                                   62

                     The conclusion reached, from the foregoing description of the effects of surface
                     separation, is somewhat disturbing since it implies that the volume of equilibrium oil
                     collected in the stock tank is dependent on the manner in which the oil and gas are
                     separated. This in turn means that the basic PVT parameters B o and R s which are
                     measured in terms of volume "per stock tank barrel" must also be dependent on the
                     manner of surface separation and cannot be assigned absolute values.

                     The only way to account for the effects of surface separation is to perform a series of
                     separator tests on oil samples as part of the basic PVT analysis, and combine the
                     results of these tests with differential liberation data. Samples of oil are put in the PV
                     cell, fig. 2.8, and raised to reservoir temperature and bubble point pressure. The cell is
                     connected to a single or multi-stage model separator system, with each separator at a
                     fixed pressure and temperature. The bubble point oil is then flashed through the
                     separator system to stock tank conditions and the resulting volumes of oil and gas are
                     measured. The results of such a series of tests, using a single separator at a series of
                     different pressures and at a fixed temperature, are listed in table 2.3 for the same oil as
                     described previously (tables 2.1 and 2.2).




                          Separator            Stock tank        Shrinkage factor       GOR
                         p         T          p          T                               R si  f
                       (psia)     (° F)     (psia)     (° F)       c  (stb/rb b)       (scf/stb)
                                                                     f b
                        200       80        14.7        60            .7983              512
                        150       80        14.7        60            .7993              510
                        100       80        14.7        60            .7932              515
                         50       80        14.7        60            .7834              526
                                                          TABLE 2.3
                               Separator flash expansion experiments performed on the oil sample
                                         whose properties are listed in tables 2.1 and 2.2

                     The shrinkage factor c , listed in table 2.3, is the volume of oil collected in the stock
                                            f b
                     tank, relative to unit volume of oil at the bubble point (stb/rb b), which is the reason for
                     the subscript b (bubble point). The subscript f refers to the fact that these experiments
                     are conducted under flash conditions. All such separator tests, irrespective of the
                     number of separator stages, are described as flash although, as already mentioned,
                     multi-stage separation is closer to a differential liberation. In any case, precisely what
                     the overall separation process is called does not really matter since the resulting
                     volumes of oil and gas are experimentally determined, irrespective of the title. R is
                                                                                                   si
                                                                                                    f
                     the initial solution gas oil ratio corresponding to the separators used and is measured
                     in the experiments in scf/stb.

                     Using the experimental separator flash data, for a given set of separator conditions, in
                     conjunction with the differential liberation data in table 2.2, will provide a means of
                     obtaining the PVT parameters required for field use. It is considered that the differential
                     liberation data can be used to describe the separation in the reservoir while the
                     separator flash data account for the volume changes between reservoir and stock tank.
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