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Flotation                                                                                        187



                   concentration difference between an equilibrium    falls thought the air. Air bubbles are entrained as
                   level and that existing at a given time.           the water falls into the water pool below and is
            Mole fraction: Ratio of molecules of gas i in a given volume  believed by some to be where most of the gas trans-
                   to the total number of molecules of all species with  fer occurs.
                   number of molecules expressed as moles.     Vacuum flotation: A technology that imposes a negative
            Nozzle: Convergence, then divergence of a pipe.           pressure on the surface of the flotation tank. Gas
            Packing: A material or plate system within a saturator that is  precipitation may occur if the incoming flow of
                   intended to cause bifurcations of the water stream to  water to be treated is ‘‘saturated’’ with respect to
                   create a substantial interfacial area of water. The  the local atmosphere of the raw water and would be
                   packing may be a granular media or a system of     more successful at low elevation.
                   plates staggered one above the other or ‘‘rings’’ of
                   various sorts. An airflow occurs counter-current  REFERENCES
                   within the pores of the packing material so as to
                   come into contact with the water. The water flow  de Rijk, S. E., Jaap, H. J. M., van der Graaf, J. M., and den Blanken,
                   through the packing material must be ‘‘unsaturated’’  J. G., Bubble size in flotation thickening, Water Research,
                   so as to maintain a high water surface area (which is  28(2):465–473, 1994.
                   the intent of the packing material).        Eckenfelder, W. W., Jr., Rooney, T. F., Burger, T. B., and Gruspier,
                                                                    J. T., Chapter 2–10, in: McCabe, J., and Eckenfelder, W. W.,
            Partial pressure: According to Dalton’s law, the partial pres-
                                                                    Jr.,  Biological  Treatment  of  Sewage  and  Industrial
                   sure of a gas i is proportional to its mole fraction.
                                                                    Wastes (Volume II, Anaerobic Digestion and Solids-Liquid
            Phenolphthalein: An indicator that changes color from pink  Separation), Reinhold Publishing Corporation, New York,
                   at pH < 8.3 to colorless when pH   8.3, as in titra-  1958.
                   tion with N=50 sodium hydroxide solution to deter-  Edzwald, J. K., Principles and applications of dissolved air flotation,
                   mine  dissolved  carbon  dioxide  concentration  Water Science and Technology, 31(3–4):1–23, 1995.
                   (Sawyer and McCarty, 1967, p. 67).          Edzwald, J. K. and Walsh, J. P., Dissolved Air Flotation: Laboratory
                                                                    and Pilot Plant Investigations, American Water Works Asso-
            Reaction zone: Zone in flotation basin just after bubble for-
                                                                    ciation Research Foundation, Denver, CO, 1992.
                   mation and as the particle stream enters in the flow
                                                               Fukushi, K., Matsui, Y., and Tambo, N., Dissolved air flotation:
                   Q to provide the opportunity for bubble–particle  Experiments and kinetic analysis, Aqua, 47(2):76–86, 1998.
                   contacts. Same as ‘‘contact zone,’’ which was the  Haarhoff, J., Factors influencing bubble formation in dissolved air
                   term adopted by a consensus of persons discussing  flotation, International Association of Water Quality Year-
                   the terminology at the 1994 International Joint  book, 1994–95, 1995.
                   Specialized Conference on Flotation Processes in  Haarhoff, J. and Rykaart, E. M., Rational design of packed
                                                                    saturators, Water Science and Technology, 31(3–4):179–190,
                   Water and Sludge Treatment, Orlando, Florida,
                                                                    1995.
                   April, 1994.
                                                               Haarhoff, J. and van Vuuren, L., Design parameters for dissolved air
            Recycle: The portion of the flow that leaves the flotation  flotation in South Africa, Water Science and Technology,
                   basin that is returned to the saturator to pick up  31(3–4):203–212, 1995.
                   dissolved air and then return to the flotation tank.  Hendricks, D. W., Oxidative Liquor Return to the Eimco Clari-
            Recycle ratio: The fraction, r, of the flow, Q, that is recycled,  Thickener, The Eimco Corporation, Internal Report, Salt
                   i.e., R, to pass through the saturator, i.e., R=Q.  Lake City, UT, 1966.
                                                               Kalinske, A. A., Flotation in waste treatment, Chapter 2–7, in:
            Saturator: A tank under pressure that has some means of
                                                                    McCabe, J. and Eckenfelder, W. W., Jr., Biological Treatment
                   creating an interfacial area between air and water.
                                                                    of Sewage and Industrial Wastes (Volume II, Anaerobic
                   One method is to use a ‘‘packing.’’ Another is to  Digestion and Solids-Liquid Separation), Reinhold Publishing
                   create a high surface area of air bubbles within the  Corporation, New York, 1958.
                   saturator.                                  Leopold, Dissolved Air Flotation, brochure, The F.B. Leopold
            Separation zone: The zone in the flotation basin after the  Company, Inc., Zelienople, PA, 8pp., 1996 (revised 2001,
                   contact zone for particle–bubble agglomerates to rise  2003).
                                                               Masterson, E. M. and Pratt, J. W., Application of pressure flotation
                   to the surface.
                                                                    principles to process equipment design, Chapter 2–8, in:
            Skimmer: Horizontal blades that traverse the surface of the
                                                                    McCabe, J. and Eckenfelder, W. W., Jr., Biological Treatment
                   flotation basin and are translated in the longitudinal  of Sewage and Industrial Wastes (Volume II, Anaerobic
                   direction by means of a chain drive.             Digestion and Solids-Liquid Separation), Reinhold Publishing
            Transport coefficient: The ratio of the number of bubbles  Corporation, New York, 1958.
                   contacting floc particles to the number of bubbles in  Matsui, Y., Fukushi, K., and Tambo, N., Modeling, simulation, and
                   a given volume within the contact zone.          operational parameters of dissolved air flotation, Aqua, 47(1):
                                                                    9–20, 1998.
            Unpacked saturator: Saturator without packing. The water
                                                               Nemerow, N. L., Liquid Wastes of Industry, Theories, Practices, and
                   enters the saturator at the top and falls through air at
                                                                    Treatment, Addison-Wesley, Reading, MA, 1971.
                   high pressure to a pool of water at the bottom of the  Ødegaard, H., Optimization of flocculation=flotation in chemical
                   tank. The entering water may impinge against a   wastewater treatment, Water Science and Technology,
                   splash plate to increase the interfacial area as it  31(3–4):73–82, 1995.
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