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Cake Filtration                                                                                  427



                                                               particle size and distribution, pore size and distribution,
                                                               permeability, specific gravity, and dry bulk densities.
                                                               Manufacturers designate their respective products by
                                                               ‘‘grade,’’ for example, Celite-560e. Table 14.1 lists selected
                                                               properties of different DE grades as designated by two
                                                               manufacturers, that is, Celitet (Celite=World Minerals Inc.,
                                                               Lompoc, California) and Celatomt (Eagle-Picher, Inc., Reno,
                                                               Nevada). The grades of diatomite are listed in an ascending
                                                               order of particle size, which corresponds to increasing pore
                                                               size and increasing permeability. As seen, the median particle
                                                               sizes are in the range of 7   d(diatoms) 50   100 mmand
                                                               median pore sizes are proportionately smaller, that is, in the
                                                               range of 1.5   d(pore) 50   22 mm. Figure 14.6 shows size
            FIGURE 14.5  Ore ‘‘chunk’’ as obtained from mining operation
                                                               distributions for several grades of Celitet, which show that for
            (ore from Ray McIndoe, c. 1984).
                                                               each grade a distribution exists, which results in the void volume
                                                               being filled to a large extent. The grades are differentiated
            rotary kilns, followed by further milling and classifying; the  by their d(50) sizes.
            resulting powder is light pink in color. A ‘‘flux calcined’’
            diatomite is manufactured by adding a ‘‘flux,’’ that is, soda
            ash, before the calcining step, which gives still coarser  14.1.3 ATTRIBUTES
            grades of DE, which are white in color (Kadey, 1975,
                                                               Some of the merits of DE filtration include compact size, low
            p. 620).
                                                               operation and maintenance costs, simplicity of operation, and
              With respect to Celitet, the finest grade is Filter-Celt,a
                                                               a system that can be shut down quickly and started quickly
            ‘‘natural’’ DE, which has been selectively quarried, dried,
                                                               (Spenser and Collins, 1995, p. 72). Examples are listed which
            milled, and air classified. Three calcined grades of DE
                                                               illustrate the range of contextual situations.
            include Celite 505t, Standard Super-Celt, and Celite 512t
            (Johns Manville Brochure FA-304 6-80, p. 7). The flux-cal-
                                                                  . Meeting summer peaking demand. Example: The DE
            cined grades include Hyflo Super-Celt, Celite 501t, Celite
                                                                    plant at Vacaville, California is operated 8 h per day
            503t, Celite 535t, Celite 545t, Celite 540t, and Celite 560t
                                                                    only during the summer.
            (McIndoe, 1969a, p. 52). The flux-calcined products have a  . Small footprint. Example: To treat the Croton water
            more open pore structure within the bulk of the material
                                                                    supply for New York, a diatomite plant was pro-
            (i.e., not within the individual particles).
                                                                    posed to be located in Jerome Park; Delaware
              The finished product is packaged in 23 kg (50 lb) bags or
                                                                    would utilize a smaller land area than rapid filtration.
            shipped bulk in trucks or box cars; bulk loading is pneumatic.  . Cost competitive. Example: For Georgetown, Color-
            The average cost per ton was $55=metric ton ($50=U.S. ton),
                                                                    ado a cost comparison between diatomite filtration
            1960–1962; in 1972, the cost was $72=metric ton ($65=U.S.
                                                                    and a rapid filtration pilot plant in 1986 indicated
            ton). The total world production in 1972 was 2.2 million
                                                                    lower annual costs using diatomite (Wirsig, 1986).
            metric tons (2 million U.S. tons) (Kadey, 1975, p. 625).  . Automated operation. Example: Hearst Castle in
                                                                    California has a varying demand for drinking water
            14.1.2.4  Characteristics of Media
                                                                    over the annual cycle; two DE plants, rated at 113
            The properties of diatomite are based in part on its method of
                                                                    L=min (30 gpm) and 155 L=min (41 gpm), serve the
            production, that is, whether it is a natural, calcined, or flux-
                                                                    demand pattern. The plant is operated by PLC (pro-
            calcined material. The properties of interest include color,
                                                                    grammable logic controller), that is, pre-coat circu-
                                                                    lates until turbidity is <0.5 NTU, then the unit
                                                                    switches to produce treated water, the unit stops at
                                                                    241 kPa (35 psi), and goes into the backwash mode
                BOX 14.1   INTERNATIONAL DIATOMITE
                                                                    (Rogers, 1997, p. 8).
                       PRODUCER’S ASSOCIATION
                                                                  . Filtration is needed to follow another process.
              The International Diatomite Producer’s Association    Example: The water source for Lompoc, California
              (IDPA) was formed in 1988 to provide a central office  is a hard groundwater (782 mg=L as CaCO 3 ), which
              to promote the use of diatomite. The IDPA represents  is treated by lime soda. The effluent turbidity from
              all diatomite producers who have elected to belong. The  this process is about 2 NTU. The DE plant that
              association provides information about diatomite and  follows the softening treatment produces a finished
              may act as a conduit from interested parties to the   water with about 0.1 NTU (Rogers, 1997, p. 7).
              diatomite producers regarding the availability of the  . Cysts in ambient source waters are a particular issue.
              product, its characteristics, and cost.               Example: DE has demonstrated high removals, that
                                                                    is, 4 < log R < 6 for cysts of Endameba histolytica,
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