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Mechanical Design and Operation of Alkanolamine Plants 269
This chart can be used in estimating the amount of methane (or dry natural gas) which will
be dissolved in a treating solution and the quantity which will remain after an equilibrium
flash separation. Data on the solubility of methane and ethane in aqueous monoethanolamine
and diethanolamine solutions, either free of acid gas or partially saturated with H2S or C02
were reported by Lawson and Garst (1976). Selected values from this study are shown in
Tables 3-9 and 3-10. It should be noted that hydrocarbon gases are appreciably more soluble
in amine solutions containing no dissolved acid gases than in solutions containing either one
or both of the acid gases.
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Units,” API Recommended Practice 945, 1st Edition, August, American Petroleum Insti-
tute, Washington, D.C.
Austgen, D. M., Rochelle, G. T., and Chen, C. C., 1991, “Model of Vapor-Liquid Equilibria
for Aqueous Acid Gas-Alkanolamine Systems, 2. Representation of HzS and COz Solubil-
ity in Aqueous MDEA and C02 Solubility in Aqueous Mixtures of MDEA with MEA or
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Bacon, T. R., 1987, ‘’Amine Solution Quality Control Through Design, Operation, and Com-
tion,” Proceedings 1987 Gas Conditioning Confeence, Univ. of Oklahoma, Norman, OK.
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Conference Proceedings, Univ. of Oklahoma, Norman, OK.
Bacon, T. R., Krohn, J. V., Lewno, J. A., and Wolcott, R. A., 1986, “Alternative Economic
Solutions for Amine Reclaiming,” paper presented at the Sixty-Fifth Gas Processors Asso-
ciation, March 10-12, San Antonio, TX.
Bagdasarian, A. J., Shargay, C. A., and Coombs, J. W., 1991, “Stress Corrosion Cracking of
Carbon Steel in DEA and ‘ADP’ Solutions,” Materials Performance, May, pp. 63-67.
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67-72.
Ballard, D., 1966, “How to Operate an Amine Plant,” Hydro. Process., Vol. 45, No. 4
(April), pp. 137-144.
Ballard, D., 1986A, “Cut EnergyKhemicaVCorrosion Costs in Amine Units,” Proc. of ne
SixV-Fgth Annual Convention (Gas Processors Assoc.), Tulsa, OK, pp. 223-236.
Ballard, D., 1986B, ‘Techniques to Cut EnergyKorrosiodChemical Costs in Amine Units,”
Proceedings 1986 Gas Conditioning Conference, Univ. of Oklahoma, Norman, OK.
Ballard, D., and von Phul, S. A., 1991, “Cut Filtration Costs by 80%,” Chem. Eng. Prog..
May, pp. 65-68.
Berlie, E. M., Estep, J. W., and Ronicker, F. J., 1965, Chem. Eng. Prog., Vol. 61, April, pp.
82-85.
Berry, W. E., 1982, “Effect of COz on Corrosion of Line Pipe,” paper presented at the Amer-
ican Gas Assoc. Transmission Conference, Chicago, IL, May 17-19.

