Page 112 - Gas Wettability of Reservoir Rock Surfaces with Porous Media
P. 112

96      Gas Wettability of Reservoir Rock Surfaces with Porous Media



                     250,000                            200,000
                                       F1s              150,000         F1s
                     optoelectronic strength/CPS  150,000  O1s  optoelectronic strength/CPS  100,000  O1s  N1s  C1s
                     200,000

                     100,000
                                                        50,000
                      50,000
                        0                      C1s         0
                                                           1400  1200  1000  800  600  400  200  0
                         1400  1200  1000  800  600  400  200  0
                                                                     Combined line/eV
                                   Combined line/eV
                                      (A)                               (B)
          FIGURE 3.2
          XPS analysis of fluorinated acrylate polymer (A) F06-AA, (B) F06-AA-DA.


                                  2.5

                                  2.0
                                 Absorptivity  1.5


                                  1.0

                                  0.5

                                  0.0
                                    240      260       280       300       320
                                                  Wave length/nm
          FIGURE 3.3
          Ultraviolet visible absorption spectra of F06-AA-DA.



                            from amine hydrochloride. Thus, the result of XPS illustrates that dopamine has
                            accessed fluorinated acrylate polymer, and is consistent with infrared analysis.


                            3.2.1.2.3   Analysis of Ultraviolet-visible Spectrum (UV-vis)
                            Fluorinated acrylate polymer was dissolved in N,N- DMF to prepare a solution
                            with certain concentration. It was tested at room temperature with scanning
                            range of 250B310 nm, and scanning speed of 440 nm/min. The experimental
                            result is shown in Fig. 3.3.
                            It can be seen from uv-visible spectroscopy (Fig. 3.3) that F06-AA-DA exhibits
                            an absorption peak at 284 nm. It shows that the polymer contains catechol
                            functional groups, indicating that dopamine is introduced in the polymer.
   107   108   109   110   111   112   113   114   115   116   117