Page 114 - Gas Wettability of Reservoir Rock Surfaces with Porous Media
P. 114

98      Gas Wettability of Reservoir Rock Surfaces with Porous Media



                                   70.0
                                  Recovery rate of imbibition/%  60.0  compare
                                               G04-AA-DA
                                   50.0
                                   40.0
                                   30.0
                                   20.0
                                   10.0
                                    0.0
                                      0    20   40  60   80   100  120  140
                                                     Time/min
          FIGURE 3.4
          Effect of wettability change on imbibition degree of gas/water system.


                                    Recovery rate of imbibition/%  50.0  compare
                                      60.0


                                      40.0
                                      30.0
                                      20.0
                                      10.0
                                      0.0
                                                         40
                                                             50
                                         0   10  20  30  G04-AA-DA  60  70
                                                     Time/min
          FIGURE 3.5
          Effect of wettability change on the imbibition degree of oil/gas system.


                            The experimental result of oil/gas system is shown in Fig. 3.5. When the core
                            is untreated, oil seeps spontaneously to replace the air, and imbibition rate is
                            53.9%. Imbibition of cores treated with polymer F06-AA-DA solution is
                            reduced to 48.1%. Therefore, when cores are treated with fluoroacrylate poly-
                            mers grafting dopamine, wettability of core surface is altered from preferential
                            liquid wettability to gas wettability, which is equivalent to the contact angle
                            test result. Also, note that the gas-wetting alteration degree of such polymers is
                            stronger than that of oil/gas system.

                            3.2.1.2.6   Flushing Resistance Test
                            Flushing resistance test of cores treated with polymer was conducted. The cores
                            were immersed in a polymer with certain concentration for 6 hours and
                            divided into three groups: one group was directly flushed with distilled water
                            and dried; another group was dried and then flushed with distilled water for
                            the same time; and the third group was directly dried after treatment. Finally,
                            the contact angle of distilled water on treated cores was measured. The results
                            are shown in Fig. 3.6.
   109   110   111   112   113   114   115   116   117   118   119