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406   CHAPTER 13



           Mg/Ca ratio for seawater is calculated (Hardie, 1996).   If the Earth’s surface was entirely covered by an
           During the resulting periods of low Mg/Ca ratio, asso-  ocean, the resulting westerly directed, equatorial ocean
           ciated with high sea level stands, nonskeletal carbonates   current, and the intermediate latitude easterly directed,
           are composed of (low magnesium) calcite, and marine   circumpolar currents, would bracket irregular “gyres,”
           evaporites are characterized by late forming KCl   circulating clockwise in the northern hemisphere, and
           (sylvite), and an absence of Mg salts. By contrast, the   anticlockwise in the southern hemisphere. In this situ-
           periods of high Mg/Ca ratio are characterized by non-  ation the world-encircling equatorial and circumpolar
           skeletal carbonate deposits composed of high magne-  currents would tend to inhibit the transfer of heat by
           sium calcite and aragonite (a polymorph of calcite), and   surface currents from low to high latitudes, and the
           marine evaporites in which MgSO 4  formed during the   temperature gradient between the equator and the

           final stages of evaporation. The former periods have   poles would be accentuated. As a consequence, sea ice
           been termed periods of “calcite seas,” and are thought   might form in the polar oceans. However, land masses
           to be associated with high pCO 2  and high surface tem-  with north–south trending shorelines in low and inter-

           peratures; i.e. a “Greenhouse Earth” such as that which   mediate latitudes, will deflect the equatorial and cir-
           probably characterized the Cretaceous. The periods of   cumpolar currents, to the right in the northern
           high Mg/Ca ratio have been designated as periods of   hemisphere, and to the left in the southern hemisphere,
           “aragonite seas.” These appear to correlate with times   thereby intensifying the gyres, and transferring heat
           of low pCO 2 , and low surface temperatures, and include   from the tropics to higher latitudes by means of western
           ice ages, i.e. an “Icehouse Earth”.          boundary currents. In this scenario the temperature
             Variations in pCO 2  in the atmosphere in the geologic   gradient is reduced. A classic example at the present day
           past are thought to have been largely due to the outgas-  is the Gulf Stream of the western North Atlantic, which
           sing of CO 2  from volcanic activity. Thus eustatic changes   warms the air above the ocean in the extreme North
           in sea level, changes in seawater chemistry, and varia-  Atlantic, thereby ameliorating the climate of Iceland
           tions in the concentration of CO 2  in the Earth’s atmo-  and northwest Europe. The opening or closing of gate-
           sphere in the past might all be related to variations in   ways for the equatorial or circumpolar currents, as a
           the rates of sea fl oor spreading and plume activity.  result of continental drift, can, therefore, have
                                                        pronounced effects on the Earth’s climate (Smith &
                                                        Pickering, 2003).
                                                          During the past 200 Ma the supercontinent of Pangea
           13.1.2  Changes in oceanic                   has progressively rifted apart. The resulting fragments
           circulation and the                          have drifted across the face of the globe, such that a
                                                        continuous tropical seaway, the neo-Tethys, was formed,
           Earth’s climate                              and subsequently closed, and a southern ocean gradu-
                                                        ally opened up around Antarctica (Figs 13.2–13.7). By
           Two of the most signifi cant influences on the Earth’s   the mid-Cenozoic, a complete southern circumpolar

           climate are the concentration of greenhouse gases in   current came into existence, which isolated and insu-
           the atmosphere (Sections 5.7, 13.1.1), and the extent,   lated Antarctica, and was probably instrumental in trig-

           distribution, and bottom topography of the oceans.   gering the first major build-up of the Antarctic ice cap
           The confi guration of the ocean basins affects the trans-  (Kennett, 1977).
           port of heat in the oceans, by surface currents and   At the beginning of the Mesozoic Era, 250 Ma ago,
           deep-water circulation, thereby affecting the tempera-  the supercontinent of Pangea extended from pole to
           ture and moisture content of the atmosphere over   pole (Fig. 13.2), without extensive polar landmasses in
           oceanic areas. Surface currents are essentially wind   either hemisphere. Strong western boundary currents
           driven, and, therefore, largely determined by the circu-  off the eastern shores of Pangea would have trans-
           lation of the atmosphere. The rotation of the Earth,   ported warm water to high latitudes, preventing the
           and the concentration of incoming solar radiation   formation of ice-sheets and warming the east-facing
           within the tropics, produces surface easterly (trade)   coasts relative to the west. The interior of the supercon-
           winds at low latitudes, westerlies at intermediate   tinent would have had strong seasonal extremes. By
           latitudes, and easterlies at high latitudes (greater   160 Ma (Fig. 13.3) a low latitude east–west seaway had
           than 60°).                                   started to open up, between what is now North America
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