Page 448 - Handbook of Thermal Analysis of Construction Materials
P. 448

Section 3.0 - Jet Set (Regulated Set) Cement                 423
















































                              Figure 17. DTA curves of C A •CaF  paste with and without calcium sulfates. (S–/A =
                                                   11
                                                          2
                                                     7
                              1.0, w/s = 0.60, 20°C). [14]

                                     The influence of a gypsum addition is also illustrated in Fig. 17.
                              The increase in the quantity of ettringite, the decrease of gypsum, and the
                              appearance of monosulfate hydrate are indicated by the relevant peaks at
                              120°C (270°C), 160°C, and 200°C respectively. The presence of hemihy-
                              drate resulted in the formation of both ettringite and gypsum (confirmed
                              by XRD). The peaks in the system containing hemihydrate in Fig. 17
                              (120–140°C, 270°C) support the XRD results.
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