Page 164 - Handbook Of Multiphase Flow Assurance
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160                        5.  Flow restrictions and blockages in operations

                 TABLE 5.5  Data for paraffin deposits collected from various depths of the same well
                                       Composition (wt%)
                                                                Melt
                 Paraffin sample         Resins, via   Solid    temperature   Residue (oils)
                 depth (m)  Asphaltenes  silica gel  hydrocarbons  (°C)     (wt%)       Loss (wt%)
                 36          2.2         8.9         64.8       72          21.8        2.3
                 88.5        1.7         6.2         65.7       72          22.0        4.4
                 133.5       1.6         7.9         64.0       74          26.3        0.2
                 193.5       2.3         6.4         59.1       75          28.7        3.5
                 328.5       2.1         5.9         53.8       75          33.9        4.3
                 448.5       2.7         7.8         49.1       77          35.0        5.4


                 Structure

                   Wax crystal habit depends on the cooling rate. Fast cooling leads to many small crystals.
                 Slow cooling leads to fewer large crystals. Wax usually crystallizes as 2-dimensional platelets.


                 Wellbore and reservoir plugging

                   Deposit thickness was reported for wellbores and surface gathering lines for Devonian
                 paraffinic oil production in Tatarstan, Russia (Mazepa, 1965) as shown in Fig. 5.32. The author
                 also reported the microphotographic research on adhesion on a steel plate of precipitated
                 paraffin particles flowing in oil. The study indicated that particles sized between 0.002 and
                 0.2 mm adhered to the steel plate.
                   Production operating parameters for the above wells are summarized in Table 5.6 below.
                   The wells 4136 and 4138 were producing undersaturated oil, at pressure above the bubble
                 point. The author (Mazepa, 1965) produced the first proof that paraffin deposition may occur
                 from undersaturated flowing oil. Additional results for 40 wells were also presented in this
                 work.
                   The author indicates that the relatively low length of sections with wax deposition for
                 low-rate wells was caused by the stratified multiphase flow of oil and gas. This flow regime
                 ended at a relatively short distance from wellheads. The stratified flow in the gathering lines
                 was confirmed in the field using radioactive density meter, sample valves, and transparent
                 spools installed on the pipelines. The critical flow rate at which the stratified flow may still
                 occur was determined from the critical Froude parameter (which accounts for the effect of
                 gravity on flow).
                                                               )
                                                               2
                                          2
                                                                      5
                                        Q =  Fr ( 1− Gasfraction π 2  g D / 16
                                               crit
                                                              ν
                                                          2
                                                   Fr crit  = ω /  g ( )
                                                          c
                   Q = oil flow rate, D = pipe diameter, ω c  = mixture velocity, g = gravity acceleration, and
                 ν = hydraulic depth.
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