Page 175 - Handbook of Thermal Analysis of Construction Materials
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158                 Chapter 4 - Introduction to Concrete Admixtures


                                     The strength of a cement, mortar, or concrete containing a Ca-
                              formate may depend on the cement composition. Geber [53]  found that the
                              early and later strengths in mortar depended on the C A/SO  ratio of the
                                                                              3
                                                                                   3
                              cement. The compressive strength increase over the control at C A/SO
                                                                                        3     3
                              ratios (at 1 day and 2% Ca formate) of 2.44, 3.32, 4.34, 5.00, and 7.22 were
                              3, -14, 25, 88, and 70% respectively. It is suggested that to derive the
                              effectiveness of formate, C A/SO  ratios higher than 4 should be preferred.
                                                           3
                                                     3
                                     Generally, Ca formate increases the early strength of concrete. In
                              Fig. 8, the results on the effect of 2% and 4% Ca formate indicate that the
                              strengths are increased in the first 24 hours. [54]  At lower dosages, the
                              strength development may not be very significant. In combination with
                              sodium nitrite, Ca formate accelerates the early strength development in
                              cement to a significant extent. In comparison with the reference specimen
                              without an admixture, the combination admixture increases strengths by
                              125, 70, 47, and 23% at 18 hrs, 1 day, 3 days, and 7 days, respectively. [55]








































                              Figure 8. Influence of calcium formate on early strength of concrete.
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